Synthesis and Optical Properties of Novel Strontium Tetranitrophthalocyanine

Silviu  GROZA; Bianca  STOEAN; Adriana  GROZAV; Ana-Maria  CRĂCIUN; Castelia  CRISTEA; Luminița SILAGHI-DUMITRESCU; Dan Ioan  PORUMB

doi:10.24193/subbchem.2023.4.02

Synthesis and Optical Properties of Novel Strontium Tetranitrophthalocyanine

Authors

Silviu GROZA Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Corresponding author: adriana.ignat@umfcluj.ro. https://orcid.org/0000-0002-6282-5257
Bianca STOEAN Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: bianca.stoean@ubbcluj.ro. https://orcid.org/0000-0001-6313-6018
Adriana GROZAV Department of Organic Chemistry, “Iuliu Hatieganu” University of Medicine and Pharmacy, Cluj-Napoca, Romania. Email: adriana.ignat@umfcluj.ro. https://orcid.org/0000-0001-5800-0896
Ana-Maria CRĂCIUN Nanobiophotonics and Laser Microspectroscopy Center, Interdisciplinary Research Institute in Bio-Nano-Sciences, Babes-Bolyai University, Cluj-Napoca, Romania. Email: ana.gabudean@ubbcluj.ro. https://orcid.org/0000-0002-6561-0972
Castelia CRISTEA Faculty of Chemistry and Chemical Engineering, Babeș-Bolyai University, Cluj-Napoca, Romania. Email: castelia.cristea@ubbcluj.ro. https://orcid.org/0000-0003-1138-2596
Luminița SILAGHI-DUMITRESCU Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: lusi@chem.ubbcluj.ro. https://orcid.org/0000-0001-8800-4839
Dan Ioan PORUMB Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: ioan.porumb@ubbcluj.ro. https://orcid.org/0000-0001-6388-2686

DOI:

https://doi.org/10.24193/subbchem.2023.4.02

Keywords:

phthalocyanine; strontium-complex; UV-vis spectroscopy; fluorescence emission life time

Abstract

Two convenient alternatives for the synthesis of metal(II) 2,9,16,23-tetranitrophthalocyanines (TNPc) were applied in the synthesis of the novel Strontium(II)TNPc and its Zinc(II)TNPc, Copper(II)TNPc and Cobalt(II)TNPc analogues. The thermal activation required for the tetramerization of the phthalic acid derivatives used as substrates (4-nitro-phthalimide or 4-nitrophthalodinitrile) was provided by convective heating in solution or solvent free conditions. The optical properties of the synthesized metal(II)TNPc were compared by means of UV-vis spectroscopy. In solution, the novel Sr(II)TNPc was characterized by absorption bands with maxima situated around 690 nm (similar to Cu(II)TNPc), while its fluorescence emission maxima lays close to Zn(II)TNPc (710 nm), with a three times longer fluorescence emission life time in solid state (3.04 ns).

References

A. Gök, E. B. Orman, Ü. Salan, A. R. Özkaya and M. Bulut, Dye. Pigment., 2016, 133, 311–323.

R. A. S. Ali, J. Keshavayya, A. S. Jagadisha, S. D. Umesha, K. N. Gujjar, S. A. Narasimha, D. G. Prasanna and E. Nagaraja, Mater. Today Proc., 2021, 49, 644–649.

M. Pişkin, J. Photochem. Photobiol. A Chem., 2023, 435, 114325.

Y. Baygu, N. Kabay, B. Kabay, B. Yıldız, İ. Ömeroğlu, M. Durmuş, E. Rıza Karagür, H. Akça, Ç. Ergin and Y. Gök, J. Mol. Struct., 2023, 1271, 134010.

H. M. Almuzafar, H. M. Ahmed, N. N. AlDuhaisan, A. M. Elsharif, H. Aldossary, S. Rehman, S. Akhtar and F. A. Khan, J. Saudi Chem. Soc., 2022, 26, 101436.

R. A. Barmin, E. A. Maksimova, P. G. Rudakovskaya, A. V. Gayer, E. A. Shirshin, K. S. Petrov, D. A. Terentyeva, O. I. Gusliakova, O. A. Sindeeva, O. A. Klimenko, R. N. Chuprov-Netochin, A. A. Solovev, G. Huang, A. V. Ryabova, V. B. Loschenov and D. A. Gorin, Colloids Surf. B., 2022, 219, 112856.

G. Gümrükçü Köse and G. Keser Karaoğlan, Chem. Phys., 2023, 565, 111737.

R. Borlan, M. Focsan, M. Perde-Schrepler, O. Soritau, A. Campu, L. Gaina, E. Pall, B. Pop, O. Baldasici, C. Gherman, D. Stoia, D. Maniu and S. Astilean, Biomater. Sci., 2021, 9, 6183–6202.

R. Borlan, D. Stoia, L. Gaina, A. Campu, G. Marc, M. Perde-Schrepler, M. Silion, D. Maniu, M. Focsan and S. Astilean, Molecules, 2021, 26, 1–21.

V. Rosca, L. Muresan, I. C. Popescu, C. Cristea and I. A. Silberg, Electrochem. commun., 2001, 3, 439–445.

K. I. Ozoemena and T. Nyokong, Talanta, 2005, 67, 162–168.

J. T. Engle, A. N. Allison, J. M. Standard, I. S. Tamgho and C. J. Ziegler, J. Porphyr. Phthalocyanines, 2013, 17, 712–721.

B. I. Kharisov, U. Ortiz Mendez, J. L. Almaraz Garza and J. R. Almaguer Rodriguez, New J. Chem., 2005, 29, 686–692.

J. Alzeer, P. J. C. Roth and N. W. Luedtke, Chem. Commun., 2009, 1970–1971.

C. G. Claessens, U. Hahn and T. Torres, Chem. Rec., 2008, 8, 75–97.

Downloads

Published

2023-12-20

How to Cite

GROZA, S. ., STOEAN, B. ., GROZAV, A. ., CRĂCIUN, A.-M. ., CRISTEA, C. ., SILAGHI-DUMITRESCU, L., & PORUMB, D. I. . (2023). Synthesis and Optical Properties of Novel Strontium Tetranitrophthalocyanine. Studia Universitatis Babeș-Bolyai Chemia, 68(4), 17–26. https://doi.org/10.24193/subbchem.2023.4.02