PHYSICO-CHEMICAL PROPERTIES AND CRYSTAL VIOLET ADSORPTION PERFORMANCES OF H₃PO₄ - MODIFIED MANGO SEEDS KERNEL

Ghislain Arnaud  MOUTHE ANOMBOGO; Andrada  MĂICĂNEANU; Jean Baptiste  BIKE MBAH; Chrisdel Chancelice  NDJEUMI; Liviu Cosmin  COTEŢ; Richard  KAMGA

PHYSICO-CHEMICAL PROPERTIES AND CRYSTAL VIOLET ADSORPTION PERFORMANCES OF H₃PO₄ - MODIFIED MANGO SEEDS KERNEL

Authors

Ghislain Arnaud MOUTHE ANOMBOGO Department of Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania; Laboratoire des Matériaux et Chimie Industrielle Inorganique, National Advanced School of Agro-Industrial Sciences, University of Ngaoundere; Department of Environmental Sciences, Higher Institute of the Sahel, University of Maroua, Cameroon. Corresponding author: andrada@chem.ubbcluj.ro.
Andrada MĂICĂNEANU Madia Department of Chemistry, Indiana University of Pennsylvania, Indiana, USA; Department of Chemical Engineering, Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: sanda.maicaneanu@iup.edu. https://orcid.org/0000-0002-6905-3894
Jean Baptiste BIKE MBAH Department of Applied Chemistry, National School of Agro-Industrial Sciences, University of Ngaoundere, Cameroon. Email: jbmbahgm@gmail.com. https://orcid.org/0000-0001-6152-2345
Chrisdel Chancelice NDJEUMI Department of Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania; Laboratoire des Matériaux et Chimie Industrielle Inorganique, National Advanced School of Agro-Industrial Sciences, University of Ngaoundere; Department of Environmental Sciences, Higher Institute of the Sahel, University of Maroua, Cameroon. Corresponding author: andrada@chem.ubbcluj.ro. https://orcid.org/0000-0002-0595-7106
Liviu Cosmin COTEŢ Department of Chemical Engineering, Faculty of Chemistry and Chemical Engineering, Babes-Bolyai University; Institute of Research-Development-Innovation in Applied Natural Sciences, Babes-Bolyai University, Cluj-Napoca, Romania. Email: ccosmin@chem.ubbcluj.ro. https://orcid.org/0000-0001-5306-2414
Richard KAMGA Laboratoire des Matériaux et Chimie Industrielle Inorganique, National Advanced School of Agro-Industrial Sciences, University of Ngaoundere, Cameroon. Email: jbmbahgm@gmail.com. https://orcid.org/0000-0002-3260-9094

Keywords:

H₃PO₄-modified mango seeds kernel, adsorption, Crystal Violet, kinetics, equilibrium, thermodynamics

Abstract

This study investigated the removal of Crystal Violet (CV) from aqueous solutions using H₃PO₄-modified mango seeds kernel (H₃PO₄-MSK). The adsorbent was characterized using elemental analysis, thermal analysis (TGA), scanning electron microscopy (SEM), specific surface area and pore size distribution (BET) and Fourier Transformed Infrared Analysis (FTIR). X-ray diffraction (XRD) analysis showed that H₃PO₄-MSK is a type II cellulose crystal structure, while SEM and BET analysis confirmed the macroporosity of the adsorbent. The removal efficiency of CV increased with an increase in adsorbent quantity and temperature. The adsorption capacities increased from 23.94 to 87.23 mg/g for an increase in temperature from 30 to 50^oC. Adsorption kinetics analysis indicated that pseudo-second-order and Elovich equations ﬁtted very well the adsorption of CV onto H₃PO₄-MSK. The adsorption process followed the Temkin and Langmuir isotherm models. Isotherm modelling showed that CV is loosely bound to H₃PO₄-MSK. Further thermodynamic analysis revealed that the removal of CV from aqueous solution by H₃PO₄-MSK was a spontaneous and endothermic process. The proposed adsorption mechanism involves -OH, -NH₂ and -COOH groups from the H₃PO₄-MSK surface.

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STUDIA UBB CHEMIA, Volume 61 (LXI), No. 3, September 2016

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Published

2016-09-30

How to Cite

MOUTHE ANOMBOGO, G. A. ., MĂICĂNEANU, A. ., BIKE MBAH, J. B. ., NDJEUMI, C. C. ., COTEŢ, L. C. ., & KAMGA, R. . (2016). PHYSICO-CHEMICAL PROPERTIES AND CRYSTAL VIOLET ADSORPTION PERFORMANCES OF H₃PO₄ - MODIFIED MANGO SEEDS KERNEL. Studia Universitatis Babeș-Bolyai Chemia, 61(3), 195–214. Retrieved from https://studia.reviste.ubbcluj.ro/index.php/chemia/article/view/8344