SILICA GEL MODIFIED WITH FUNCTIONALIZED CALIXARENES. PREPARATION AND CHARACTERIZATION

Raul  RANETE; Petronela M.  PETRAR; Raluca  ȘEPTELEAN; Ioana  PERHAIŢĂ; Gabriela  NEMES

SILICA GEL MODIFIED WITH FUNCTIONALIZED CALIXARENES. PREPARATION AND CHARACTERIZATION

Authors

Raul RANETE Department of Chemistry, Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Corresponding author: sgabi@chem.ubbcluj.ro.
Petronela M. PETRAR Department of Chemistry, Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: ppetrar@chem.ubbcluj.ro.
Raluca ȘEPTELEAN Department of Chemical Engineering, Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: sraluca@chem.ubbcluj.ro. https://orcid.org/0000-0003-3458-8394
Ioana PERHAIŢĂ Department of Chemistry, Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Corresponding author: sgabi@chem.ubbcluj.ro.
Gabriela NEMES Department of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: gabriela.nemes@ubbcluj.ro.

Keywords:

functionalized silica gel, calixarenes, thermal analyses, electronic microscopy

Abstract

This work presents the synthesis and characterization of novel products obtained by the chemical bonding of lower rim substituted calix[4]- and calix[8]arene macrocycles to silica gel surfaces modified with aminopropyl chains. The products were investigated by thermogravimetric analysis (DTG, EGA), surface area analysis (BET), as well as by electron microscopy (TEM, SEM).

References

C.D. Gutsche, J.F. Stoddart, Calixarenes Revisited, The Royal Society of Chemistry, Cambridge, 1998.

B. Dhawan, S.-I. Chen, C.D. Gutsche, Macromolecular Chemistry and Physics, 1997, 188 (5), 921.

A. Saponar, E.-J.Popovici, N. Popovici, E. Bica, G. Nemes, P. Petrar, I. Silaghi-Dumitrescu, Revista de Chimie, 2009, 60 (3), 278.

A. Saponar, E-J. Popovici, R. Grecu, I. Silaghi-Dumitrescu, N. Popovici, Studia UBB Chemia, 2009, 44 (4), 203.

S. Saying, M. Yilmaz, M. Tavasli, Tetrahedron, 2011, 67, 3743.

R.V. Rodik, V.I. Boyko, V.I. Kalcheno, Current Medicinal Chemistry, 2009, 16 (13), 1630.

B. Mokhtari, K. Pourabdollah, N. Dalali, Chromatographia, 2011, 73 (9-10), 829.

M. Sliwka-Kaszynka, Critical Reviews in Analytical Chemistry, 2007, 37 (3), 211.

A. Saponar, E.-J. Popovici, R. Septelean, E. Bica, I. Perhaita, G. Nemes, Revista de Chimie, 2013, 64 (1), 55.

A. Saponar, E.-J. Popovici, G. Nemes, N. Popovici, I. Perhaita, E. Bica, I. Silaghi-Dumitrescu, Revista de Chimie, 2012, 63 (3), 249.

J.S. Kim, D.T. Quang, Chemical Reviews, 2007, 107 (9), 3780.

Y. Kurusu, D.C. Neckers, Journal of Organic Chemistry, 1991, 56 (6), 1981.

E. Soto-Cantu, R. Cueto, J. Koch, P.S. Russo, Langmuir, 2012, 28 (13), 5562.

S. Sayin, F. Ozcan, M. Yilmaz, Journal of Hazardous Materials, 2010, 178 (1 - 3), 312.

C. Ding, K. Qu, Y. Li, K. Hu, H. Liu, B. Ye, Y. Wu, S. Zhang, Journal of Chromatography A, 2007, 1170 (1 - 2), 73.

K. Miyatake, O. Ohama, Y. Kawahara, A. Urano, A. Kimura, SEI Technical Review, 2007, 65.

K.C. Vrancken, L. De Coster, P.V. Der Voort, P.J. Grobet, E.F. Vansant, Journal of Colloid and Interface Science, 1995, 170 (1), 71.

B. Arkles, CHEMTECH 7, 1977, 766.

G.D. Andreetti, V. Böhmer, J.G. Jordon, M. Tabatabai, F. Ugozzoli, W. Vogt, A. Wolff, Journal of Organic Chemistry, 1993, 58, 4023.

C.D. Gutsche, L.G. Lin, Tetrahedron, 1986, 42 (6), 1633.

V. Ivanovskia, M. Bukleskia, M. Madalska, E. Hey-Hawkins, Vibrational Spectroscopy, 2013, 69, 57.

C.D. Gutsche, B. Dhawan, J.A. Levine, K.H. No, L.J. Bauer, 1983, 39 (3), 409.

V. Ivanovskia, M. Bukleskia, M. Madalska, E. Hey-Hawkins, Vibrational Spectroscopy, 2013, 69, 57.

STUDIA UBB CHEMIA, Volume 60 (LX), No. 2, Tom I, June 2015

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Published

2015-06-01

How to Cite

RANETE, R. ., PETRAR, P. M. ., ȘEPTELEAN, R. ., PERHAIŢĂ, I. ., & NEMES, G. . (2015). SILICA GEL MODIFIED WITH FUNCTIONALIZED CALIXARENES. PREPARATION AND CHARACTERIZATION. Studia Universitatis Babeș-Bolyai Chemia, 60(2), 15–26. Retrieved from https://studia.reviste.ubbcluj.ro/index.php/chemia/article/view/8425