NOVEL 1,9-DIACYL-5-(PHENOTHIAZINYL)DIPYRROMETHANE DIALKYLTIN COMPLEXES

Balázs BRÉM; Emese GÁL; Luiza GĂINĂ; Tamás LOVÁSZ; Éva  MOLNÁR; Dan Ioan PORUMB; Castelia CRISTEA

NOVEL 1,9-DIACYL-5-(PHENOTHIAZINYL)DIPYRROMETHANE DIALKYLTIN COMPLEXES

Authors

Balázs BRÉM Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: bbrem@chem.ubbcluj.ro. https://orcid.org/0000-0001-6091-5817
Emese GÁL Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: emese.gal@ubbcluj.ro. https://orcid.org/0000-0003-4324-0787
Luiza GĂINĂ Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: gluiza@chem.ubbcluj.ro. https://orcid.org/0000-0002-1328-0107
Tamás LOVÁSZ Department of Chemisty and Chemical Engineering in Hungarian Language, Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: tlovasz@chem.ubbcluj.ro. https://orcid.org/0000-0003-2923-7442
Éva MOLNÁR Institute of Chemical and Process Engineering, Department of Chemical Engineering Science, University of Pannonia, Veszprém, Hungary. Email: molnare@almos.uni-pannon.hu.
Dan Ioan PORUMB Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: ioan.porumb@ubbcluj.ro. https://orcid.org/0000-0001-6388-2686
Castelia CRISTEA Faculty of Chemistry and Chemical Engineering, “Babeș-Bolyai” University, Cluj-Napoca, Romania. Email: castelia.cristea@ubbcluj.ro. https://orcid.org/0000-0003-1138-2596

Keywords:

Dipyrromethane, Phenothiazine, Tin complexes

Abstract

New 1,9-diacyl-5-(phenothiazinyl)dipyrromethane (aphdpm) obtained by diacylation of 5-phenothiazinyl-dipyrromethane were subjected to complexation reactions with dimethyl- and di-n-butyltin(IV) dichloride which afforded complexes of the type [Me₂Sn(aphdpm)] and [(n-Bu)₂Sn(aphdpm)] respectively [where aphdpm: 1,9-diformyl-5-(phenothiazinyl)dipyrromethane and 1,9-dibenzoyl-5-(phenothiazinyl) dipyrromethane]. Plausible structures of the new tin(IV) complexes were proposed based on spectroscopic FT-IR, ¹H-,¹³C-,¹¹⁹Sn-NMR and mass spectrometry studies.

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STUDIA UBB CHEMIA, Volume 61 (LXI), No. 3, September 2016

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Published

2016-09-30

How to Cite

BRÉM, B., GÁL, E., GĂINĂ, L., LOVÁSZ, T., MOLNÁR, Éva ., PORUMB, D. I., & CRISTEA, C. (2016). NOVEL 1,9-DIACYL-5-(PHENOTHIAZINYL)DIPYRROMETHANE DIALKYLTIN COMPLEXES. Studia Universitatis Babeș-Bolyai Chemia, 61(3), 73–80. Retrieved from https://studia.reviste.ubbcluj.ro/index.php/chemia/article/view/8332