DETERMINATION OF HEAVY METALS AND LEAD-STRONTIUM ISOTOPE CHARACTERIZATION FROM MERLOT SOIL SAMPLES, DEALU BUJORULUI VINEYARD

Florin Dumitru BORA; Alina DONICI; Anamaria CĂLUGĂR; Ioan-Valentin  PETRESCU MAG; Emese GÁL; Claudiu Ioan BUNEA

doi:10.24193/subbchem.2017.4.27

DETERMINATION OF HEAVY METALS AND LEAD-STRONTIUM ISOTOPE CHARACTERIZATION FROM MERLOT SOIL SAMPLES, DEALU BUJORULUI VINEYARD

Authors

Florin Dumitru BORA Department of Physico-Chemistry and Biochemistry, Research Station for Viticulture and Enology, Targu Bujor, Galați, Romania. Email: florin.bora@usamvcluj.ro. https://orcid.org/0000-0002-8954-7779
Alina DONICI Department of Physico-Chemistry and Biochemistry, Research Station for Viticulture and Enology, Targu Bujor, Galați, Romania. Email: donicialina79@gmail.com. https://orcid.org/0000-0002-4018-2801
Anamaria CĂLUGĂR Department of Horticulture and Landscaping, University of Agricultural Sciences and Veterinary Medicine, Cluj-Napoca, Romania. Email: anamaria.calugar@usamvcluj.ro. https://orcid.org/0000-0003-2288-3783
Ioan-Valentin PETRESCU MAG Department of Agriculture, University of Agricultural Sciences and Veterinary Medicine, Cluj-Napoca, Romania. Corresponding author: florin.bora@usamvcluj.ro. https://orcid.org/0000-0002-9109-3833
Emese GÁL Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: emese.gal@ubbcluj.ro. https://orcid.org/0000-0003-4324-0787
Claudiu Ioan BUNEA Department of Horticulture and Landscaping, University of Agricultural Sciences and Veterinary Medicine, Cluj-Napoca, Romania. Email: claudiu.bunea@usamvcluj.ro. https://orcid.org/0000-0002-8954-7779

DOI:

https://doi.org/10.24193/subbchem.2017.4.27

Keywords:

heavy metals, soil profile, 207Pb/206Pb, 208Pb/206Pb, 204Pb/206Pb, 87Sr/86Sr isotope ratio

Abstract

Contamination of vineyard soils with heavy-metals has been a worldwide concern, determination of these elements being important for the wine industry. The aim of this research was to determine the concentration of different heavy metals (Cd, Pb, U, Hg, As, Sr, Co, Cu, Ni and Cr) from vineyard soil on different depths in an area of vineyard cultivation from Dealu Bujorului Galati County. In order to highlight the combination of different sources, natural or anthropogenic of heavy metals the isotopic ratios for ²⁰⁶Pb/²⁰⁷Pb, ²⁰⁸Pb/²⁰⁶Pb, ²⁰⁶Pb/²⁰⁷Pb and ⁸⁷Sr/⁸⁶Sr from soil were established. The highest concentrations for heavy metals were recorded on the surface, with increasing depth of the soil these concentrations decrease. Regarding of Pb sources (lithogenic or anthropogenic), the average ²⁰⁶Pb/²⁰⁷Pb, ²⁰⁸Pb/²⁰⁶Pb and ²⁰⁶Pb/²⁰⁴Pb ratios in soil profile increase horizons followed the order: 1.13526 (0-10 cm ²⁰⁶Pb/²⁰⁷Pb) > 1.13427 (10-20 cm ²⁰⁶Pb/²⁰⁷Pb); 2.12626 (10-20 cm ²⁰⁸Pb/²⁰⁶Pb) > 2.12472 (10-20 cm ²⁰⁸Pb/²⁰⁶Pb) and 17.36201 (10-20 cm ²⁰⁶Pb/²⁰⁴Pb) > 17.36128 (0-10 cm ²⁰⁶Pb/²⁰⁴Pb). Statistically, in the case of ²⁰⁶Pb/²⁰⁷Pb and ²⁰⁸Pb/²⁰⁶Pb there are very significant differences between the analyzed variants while ²⁰⁶Pb/²⁰⁴Pb does not show any differences in terms of distribution on the depth of the soil profile. Our results confirm that the ²⁰⁷Pb/²⁰⁶Pb, ²⁰⁸Pb/²⁰⁶Pb, ²⁰⁴Pb/²⁰⁶Pb and ⁸⁷Sr/⁸⁶Sr isotope ratio can be used to track the geographical origin of wine, discriminate between wine production regions, and be used to characterize wine terroirs for forensic purpose.

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STUDIA UBB CHEMIA, Volume 62 (LXII), No. 4, Tome II, June 2017

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Published

2017-12-29

How to Cite

BORA, F. D., DONICI, A., CĂLUGĂR, A., PETRESCU MAG, I.-V. ., GÁL, E., & BUNEA, C. I. (2017). DETERMINATION OF HEAVY METALS AND LEAD-STRONTIUM ISOTOPE CHARACTERIZATION FROM MERLOT SOIL SAMPLES, DEALU BUJORULUI VINEYARD. Studia Universitatis Babeș-Bolyai Chemia, 62(4, Tome II), 317–332. https://doi.org/10.24193/subbchem.2017.4.27