SILICON RELEASE FROM HYDROXYAPATITES IN WATER AND SIMULATED BODY FLUID

Oana  CADAR; †Petre T.  FRANGOPOL; Gheorghe  TOMOAIA; Daniel  OLTEAN-DAN; Gertrud Alexandra PALTINEAN; Aurora MOCANU; Ossi  HOROVITZ; Maria TOMOAIA-COTISEL

doi:10.24193/subbchem.2017.4.06

SILICON RELEASE FROM HYDROXYAPATITES IN WATER AND SIMULATED BODY FLUID

Authors

Oana CADAR Research Institute for Analytical Instrumentation (INCDO-INOE 2000), Cluj-Napoca, Romania. Email: oana.cadar@icia.ro. https://orcid.org/0000-0002-0879-9211
†Petre T. FRANGOPOL Faculty of Chemistry and Chemical Engineering, Research Center of Physical Chemistry, Babeş-Bolyai University, Cluj-Napoca, Romania. Corresponding author: mcotisel@chem.ubbcluj.ro.
Gheorghe TOMOAIA Department of Orthopedics and Traumatology, Iuliu Hatieganu University of Medicine and Pharmacy, Cluj-Napoca; Academy of Romanian Scientists, Bucharest, Romania. Email: tomoaia2000@yahoo.com. https://orcid.org/0000-0002-5633-6895
Daniel OLTEAN-DAN Department of Orthopedics and Traumatology, Iuliu Hațieganu University of Medicine and Pharmacy, Cluj-Napoca. Email: oltean.dan@umfcluj.ro. https://orcid.org/0000-0002-8094-8963
Gertrud Alexandra PALTINEAN Research Center of Physical Chemistry, Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: gertrud.paltinean@ubbcluj.ro. https://orcid.org/0000-0002-4000-1978
Aurora MOCANU Research Center of Physical Chemistry, Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: gertrud.paltinean@ubbcluj.ro. https://orcid.org/0000-0002-8728-045X
Ossi HOROVITZ Research Center of Physical Chemistry, Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Corresponding author: mocanu.aurora@gmail.com. https://orcid.org/0000-0002-3652-8558
Maria TOMOAIA-COTISEL Research Center of Physical Chemistry, Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: maria.tomoaia@ubbcluj.ro. https://orcid.org/0000-0002-0995-3006

DOI:

https://doi.org/10.24193/subbchem.2017.4.06

Keywords:

hydroxyapatite, silicon doped HAP, elements release, simulated body fluid

Abstract

Nanostructured hydroxyapatite (HAP) and silicon substituted hydroxyapatites (HAP-Si), with 0.47 and 2.34 wt% Si, were prepared by wet precipitation method. Their structure was investigated by X rays diffraction (XRD), FTIR spectroscopy, energy dispersive X ray (EDX) spectroscopy and their images were obtained by TEM, SEM and AFM. Their behavior in water and SBF was investigated by inductively coupled plasma optical emission spectrometry (ICP-OES) for an immersion time from 1 to 90 days. While Ca and P release from HAP is very low, the presence of Si enhances greatly their release in water, along with a continuous and long lasting Si release. In simulated body fluid, SBF, Ca, P and Mg are removed from the solution, by the formation of a new HAP enriched in Mg, while silicon is released as in water. Thus, Si doped HAP might have advantageous applications as bone and tooth materials.

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STUDIA UBB CHEMIA, Volume 62 (LXII), No. 4, Tome I, June 2017

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Published

2017-12-29

How to Cite

CADAR, O. ., FRANGOPOL, †Petre T. ., TOMOAIA, G. ., OLTEAN-DAN, D. ., PALTINEAN, G. A., MOCANU, A., … TOMOAIA-COTISEL, M. (2017). SILICON RELEASE FROM HYDROXYAPATITES IN WATER AND SIMULATED BODY FLUID. Studia Universitatis Babeș-Bolyai Chemia, 62(4, Tome I), 67–80. https://doi.org/10.24193/subbchem.2017.4.06