MECHANISMS IN THE SYNTHESIS OF FORSTERITE NANOPARTICLES BASED ON THERMODYNAMIC APPROACH

Authors

  • Alexandra AVRAM Department of Chemical Engineering, Research Center in Physical Chemistry, Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: aavram@chem.ubbcluj.ro.
  • Ossi HOROVITZ Research Center of Physical Chemistry, Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Corresponding author: maria.tomoaia@ubbcluj.ro. https://orcid.org/0000-0002-3652-8558
  • Attila-Zsolt KUN Department of Chemistry and Chemical Engineering, Hungarian Line of Study, Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: attila.kun@ubbcluj.ro. https://orcid.org/0000-0002-6337-9228
  • Ioan PETEAN Department of Chemical Engineering, Research Center in Physical Chemistry, Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: petean@chem.ubbcluj.ro. https://orcid.org/0000-0003-3274-8817
  • Gheorghe TOMOAIA Department of Orthopedics and Traumatology, Iuliu Hatieganu University of Medicine and Pharmacy, Cluj-Napoca; Academy of Romanian Scientists, Bucharest, Romania. Email: tomoaia2000@yahoo.com. https://orcid.org/0000-0002-5633-6895
  • Aurora MOCANU Research Center of Physical Chemistry, Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: aurora.mocanu@ubbcluj.ro. https://orcid.org/0000-0002-8728-045X
  • Maria GOREA Babeş-Bolyai University, Faculty of Chemistry and Chemical Engineering, Department of Chemical Engineering, 11 Arany Janos str., RO-400028, Cluj-Napoca, Romania. Email: mgorea@chem.ubbcluj.ro.
  • Firuța GOGA Department of Chemical Engineering, Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: fgoga@chem.ubbcluj.ro. https://orcid.org/0000-0001-8367-7874
  • Diana Alexandra FLOREA Department of Chemical Engineering, Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: diana_florea03@yahoo.com. https://orcid.org/0000-0003-4054-972X
  • Maria TOMOAIA-COTISEL Research Center of Physical Chemistry, Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: maria.tomoaia@ubbcluj.ro. https://orcid.org/0000-0002-0995-3006

DOI:

https://doi.org/10.24193/subbchem.2023.2.03

Keywords:

forsterite, sol-gel, precipitation method, synthesis mechanisms, thermodynamic approach

Abstract

Due to the ions in its structure, that have a variety of important roles in bone metabolism, forsterite (FS, Mg2SiO4) is a promising candidate for orthopedic and dental applications. This paper studies forsterite synthesized through two methods, namely sol-gel (FSsg) and precipitation (FSpp), based on a thermodynamic approach. Therefore, the precursor gel and precipitate were analyzed through thermal gravimetric (TG), differential thermal gravimetric (DTG) and differential scanning calorimetric (DSC) analysis. The FSsg and FSpp powders were characterized by X-ray powder diffraction (XRD) and atomic force microscopy (AFM). XRD reveals that the synthesized forsterite is of high crystallinity. As is evidenced by AFM, the average size of the nanoparticles is around 40 nm for FSsg and 30 nm for FSpp. The potential reaction mechanisms for the two synthesis routes were also established.

 

References

Gh. Tomoaia; M. Tomoaia-Cotisel; L. B. Pop; A. Pop; O. Horovitz; A. Mocanu; N. Jumate, L. D. Bobos; Rev. Roum. Chim., 2011, 56(10-11), 1039-1046.

C. Prejmerean; M. Tomoaia-Cotisel; E. Vasile; G. Furtos; L. B. Pop; M. Moldovan; C. Sarosi; I. Petean; Int. J. Nano and Biomater., 2011, 3(4), 344-359.

G. Furtos; M. Tomoaia-Cotisel; C. Garbo; M. Senila; N. Jumate; I. Vida-Simiti; C. Prejmerean; Particul. Sci. Technol., 2013, 31(4), 392-398.

Gh. Tomoaia; O. Soritau; M. Tomoaia-Cotisel; L.B. Pop; A. Pop; A. Mocanu; O. Horovitz, L. D. Bobos; Powder. Technol., 2013, 238, 99-107.

A. Mocanu; G. Furtos; S. Rapuntean; O. Horovitz; C. Flore; C. Garbo; A. Danisteanu; Gh. Rapuntean; C. Prejmerean; M. Tomoaia-Cotisel; Appl. Surf. Sci., 2014, 298, 225-235.

Gh. Tomoaia; A. Mocanu; I. Vida-Simiti; N. Jumate; L. D. Bobos; O. Soritau; M. Tomoaia-Cotisel; Mater. Sci. Eng. C, 2014, 37, 37-47.

P.T. Frangopol; A. Mocanu; V. Almasan; C. Garbo; R. Balint; G. Borodi; I. Bratu; O. Horovitz; M. Tomoaia-Cotisel; Rev. Roum. Chim., 2016, 61(4-5), 337-344.

A. Danistean; M. Gorea; A. Avram; S. Rapuntean; Gh. Tomoaia; A. Mocanu; C. Garbo; O. Horovitz; M. Tomoaia-Cotisel; Stud. UBB Chem., 2016, 61(3), 275-283.

E. Forizs; F. Goga; A. Avram; A. Mocanu; I. Petean; O. Horovitz; M. Tomoaia-Cotisel; Stud. UBB Chem., 2017, 62(4), 173-180.

A. Avram; T. Frentiu; O. Horovitz; A. Mocanu; F. Goga; M. Tomoaia-Cotisel; Stud. UBB Chem., 2017, 62(4), 93-104.

A. Mocanu; R. Balint; C. Garbo; L. Timis; I. Petean; O. Horovitz; M. Tomoaia-Cotisel; Stud. UBB Chem., 2017, 62(2), 95-103.

A. Avram; M. Gorea; R. Balint; L. Timis; S. Jitaru; A. Mocanu; M, Tomoaia-Cotisel; Stud. UBB Chem., 2017, 62(4), 81-92.

S. Rapuntean; P. T. Frangopol; I. Hodisan; Gh. Tomoaia; D. Oltean-Dan; A. Mocanu; C. Prejmerean; O. Soritau; L. Z. Racz; M. Tomoaia-Cotisel; Rev. Chim. (Bucharest), 2018, 69(12), 3537-3444.

D. Oltean-Dan; G. B. Dogaru; M. Tomoaia-Cotisel; D. Apostu; A. Mester; H. R. C. Benea; M. G. Paiusan; E. M. Jianu; A. Mocanu; R. Balint; C. O. Popa; C. Berce; G. I. Bodizs; A. M. Toader; Gh. Tomoaia; Int. J. Nanomed., 2019, 14, 5799-5816.

D. Oltean-Dan; G.-B. Dogaru; E.-M. Jianu; S. Riga; M. Tomoaia-Cotisel; A. Mocanu; L. Barbu-Tudoran; Gh. Tomoaia; Micromachines, 2021, 12(11), 1325.

A. Mocanu; P.T. Frangopol; R. Balint; O. Cadar; I.M. Vancea; R. Mantiu; O. Horovitz, M. Tomoaia-Cotisel; Stud. UBB Chem., 2021, 66(3), 195-207.

A. Mocanu; O. Cadar; P.T. Frangopol; I. Petean; Gh. Tomoaia; G.-A. Paltinean; C.P. Racz; O. Horovitz; M. Tomoaia-Cotisel; R. Soc. Open. Sci., 2021, 8(1), 201785.

S. Ramesh; A. Yaghoubi; K.Y.S. Lee; K.M.C. Chin; J. Purbolaksono; M. Hamdi; M.A. Hassan; J. Mech. Behav. Biomed. Mater., 2013, 25, 63-69.

F.S. Sayyedan; M.H. Fathi; H. Edris; A. Doostmohammadi; V. Mortazavi; A. Hanifi; Ceram. Int., 2014, 40, 10743-10748.

S. Pratapa; W.D. Handoko; U. Nurbaiti; M. Mashuri; Ceram. Int., 2017, 43, 7172-7176.

S.A. Hassanzadeh-Tabrizi; Ceram. Int., 2017, 43, 15714- 15718.

M. Gorea; M.-A. Naghiu; A. Avram; I. Petean; M. Tomoaia-Cotisel; Stud. UBB Chem., 2019, 64(2(2)), 383-392.

G. Furtos; M. A. Naghiu; H. Declercq; M. Gorea; C. Prejmerean; O. Pana; M. Tomoaia-Cotisel; J. Biomed. Mater. Res. Part B, 2016, 104(7), 1290-1301.

F.I. Wolfe; A. Cittadini; Mol. Aspects Med., 2003, 24, 3-9.

R.K. Rude; H.E. Gruber; J. Nutr. Biochem., 2004, 15, 710-716.

S. Castiglioni; A. Cazzaniga; W. Albisetti; J.A.M. Maier; Nutrients, 2013, 5, 3022-3033.

L.Y. He; X.M. Zhang; B. Liu; Y. Tian; W.H. Ma; Braz. J. Med. Biol. Res., 2016, 49(7), e5257.

P. Han; C. Wu; Y. Xiao; Biomater. Sci., 2013, 1, 379-392.

K. Dashnyam; A. El-Fiqi; J.O. Buitrago; R.A. Perez; J.C. Knowles; H.-W. Kim; J. Tissue Eng., 2017, 8, 2041731417707339.

W. Gotz; E. Tobiasch; S. Witzleben; M. Schulze; Pharmaceutics, 2019, 11(3), 117.

M. Gorea; M.-A. Naghiu; M. Tomoaia-Cotisel; Ceram.-Silk., 2013, 57(2), 87-91.

R. Gheitanchi; M. Kharaziha; R. Emadi; Ceram. Int., 2017, 43, 12018-12025.

K.B. Devi; B. Tripathy; A. Roy; B. Lee; P.N. Kumta; S.K. Nandi; M. Roy; ACS Biomater. Sci. Eng., 2019, 5, 530-543.

F. Tavangarian; R. Emadi; Ceram. Int., 2011, 37, 2275-2280.

M.A. Naghiu; M. Gorea; E. Mutch; F. Kristaly; M. Tomoaia-Cotisel; J. Mater. Sci. Technol., 2013, 29(7), 628-632.

G. Krishnamurithy; S. Mohan; N.A. Yahya; A. Mansor; M.R. Murali; H.R.B. Raghavendran; R. Choudhary; S. Sasikumar; T. Kamarul; PLoS ONE, 2019, 14(3), e0214212.

M. Kharaziha; M.H. Fathi; J. Mech. Behav. Biomed. Mater., 2010, 3, 530-537.

S. Ni; L. Chou; J. Chang; Ceram. Int., 2007, 33, 83-88.

M. Kheradmandfard; S.F. Kashani-Bozorg; A.H. Noori-Alfesharaki; A.Z. Kharazi; M. Kheradmandfard; N. Abutalebi; Mat. Sci. Eng. C, 2018, 92, 236-244.

K.B. Devi; B. Tripathy; P.N. Kumta; S.K. Nandi; M. Roy; ACS Biomater. Sci. Eng., 2018, 5, 2126–2133.

L. Chen; G. Ye; Q. Wang; B. Blanpain; A. Malfliet; M. Guo; Ceram. Int., 2015, 41(2(A)), 2234–2239

L. Mathur; S.K.S. Hossain; M.R. Majhi; P.K. Roy; Bol. Soc. Esp. Ceram. Vidr., 2018, 57(3), 112–118.

F. Ghariani; R. Fezei; A.H. Hamzaoui; J. Sol-Gel Sci. Technol., 2018, 88, 100-104.

A.M. Nojehdeh; F. Moghaddam; M.T. Hamedani; J Sol-Gel Sci Technol., 2022, 107(1), 1-9.

R.Y.S. Zampiva; L.H. Acauan; L. Moreira dos Santos; R.H. Ribeiro de Castro; A. Kopp Alves; C. Perez Bergman; Ceram. Int., 2017, 43(18), 16225-16231.

A. Avram; M. Gorea; S. Rapuntean; A. Mocanu; G.A. Paltinean; C. Varhelyi Jr.; O. Horrovitz; M. Tomoaia-Cotisel; Rev. Chim. (Bucharest), 2020, 71(1), 13-21.

A. Douy; J. Sol-Gel Sci. Technol., 2002, 24, 221-228.

R. Saidi; M. Fathi; H. Salimijazi; M. Mohammadrezaie; J. Sol-Gel Sci. Technol., 2017, 81(3), 734-740.

U. Nurbaiti; Darminto; Triwikantoro; M. Zainuri; S. Pratapa; Ceram. Int., 2018, 44, 5543–5549.

A. Avram; S. Rapuntean; M. Gorea; Gh. Tomoaia; A. Mocanu; O. Horovitz; Gh. Rapuntean; M. Tomoaia-Cotisel; Environ. Sci. Pollut. Res., 2022, 29, 77097–77112.

R. Choudhary; A. Chatterjee; S.K. Venkatraman; S. Koppala; J. Abraham; S. Swamiappan; Bioact. Mater., 2018, 3, 218-224.

M. Saqaei; M. Fathi; H. Edris; V. Mortazavi; N. Hosseini; Adv. Powder Technol., 2016, 27, 1922-1932.

M. Tomoaia-Cotisel; A. Tomoaia-Cotisel; T. Yupsanis; Gh. Tomoaia; I. Balea; A. Mocanu; Cs. Racz; Rev. Roum. Chim., 2006, 51(12), 1181-1185.

O. Horovitz; Gh. Tomoaia; A. Mocanu; T. Yupsanis; M. Tomoaia-Cotisel; Gold Bull., 2007, 40(4), 295-304.

U. V. Zdrenghea; Gh. Tomoaia; D.-V. Pop-Toader; A. Mocanu; O. Horovitz; M. Tomoaia-Cotisel; Comb. Chem. High Throughput Screen., 2011, 14(4), 237-247.

L.Z. Racz; G.-A. Paltinean; I. Petean; Gh. Tomoaia; L.C. Pop; G. Arghir; E. Levei; A. Mocanu; C.-P. Racz; M. Tomoaia-Cotisel; Studia UBB Chem., 2022, 67(3), 61-74.

A. Mocanu; R.D. Pasca; Gh. Tomoaia; C. Garbo; P.T. Frangopol; O. Horovitz; M. Tomoaia-Cotisel; Int. J. Nanomed, 2013, 8, 3867-3874.

C.-P. Racz; L.Z. Racz; C.G. Floare; Gh. Tomoaia; O. Horovitz; S. Riga; I. Kacso; Gh. Borodi; M. Sarkozi; A. Mocanu; C. Roman; M. Tomoaia-Cotisel; Food. Hydrocoll., 2023, 139, 1088547.

Cs.-P. Racz; S. Santa; M. Tomoaia-Cotisel; Gh. Borodi; I. Kacso; A. Pirnau; I. Bratu; J. Incl. Phenom. Macrocycl. Chem., 2013, 76, 193–199.

C. Garbo; J. Locs; M. D’Este; G. Demazeau; A. Mocanu; C. Roman; O. Horovitz; M. Tomoaia-Cotisel; Int. J. Nanomed., 2020, 15, 1037-1058.

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Published

2023-06-30

How to Cite

AVRAM, A. ., HOROVITZ, O. ., KUN, A.-Z. ., PETEAN, I. ., TOMOAIA, G. ., MOCANU, A. ., … TOMOAIA-COTISEL, M. . (2023). MECHANISMS IN THE SYNTHESIS OF FORSTERITE NANOPARTICLES BASED ON THERMODYNAMIC APPROACH. Studia Universitatis Babeș-Bolyai Chemia, 68(2), 37–51. https://doi.org/10.24193/subbchem.2023.2.03

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