THE EFFECT OF ELECTRON-RICH HETEROATOMS IN METALLABORANE CLUSTERS

Authors

  • Alexandru LUPAN Department of Chemistry and Chemical Engineering, Babes-Bolyai University, Cluj-Napoca, Romania. Email: alexandru.lupan@ubbcluj.ro. https://orcid.org/0000-0002-9353-7629
  • Amr A.A. ATTIA Department of Chemistry and Chemical Engineering, Babes-Bolyai University, Cluj-Napoca, Romania. Corresponding author: Corresponding author: alupan@chem.ubbcluj.ro. https://orcid.org/0000-0001-7020-5691
  • Robert Bruce KING Department of Chemistry, University of Georgia, Athens, Georgia, United States. Email: rbking@chem.uga.edu.

Keywords:

Metallaboranes, Density functional theory, heteroatoms, electronegativity

Abstract

The experimentally synthesized and structurally characterized metallaborane clusters containing highly electronegative heteroatoms namely (S, P, and Se) were studies by density functional theory in order to provide an insight into the influence of these heteroatoms on the polyhedral framework of metallaboranes.

References

K. Wade, Chem. Commun., 1971, 792-793.

K. Wade, Adv. Inorg. Chem. Radiochem., 1976, 18, 1-66.

D.M.P. Mingos, Nature Phys. Sci., 1972, 236, 99-102.

D.M.P. Mingos, Acc. Chem. Res., 1984, 17, 311-319.

M.F. Hawthorne, Acc. Chem. Res., 1968, 1, 281-288.

J.L. Little, J.G. Kester, J.C. Huffman, L.J. Todd, Inorg. Chem., 1989, 28, 1087-1091.

R. McLellan, N.M. Boag, K. Dodds, D. Ellis, S.A. Macgregor, D. McKay, S.L. Masters, R. Noble-Eddy, N.P. Platt, D.W.H. Rankini, H.E. Robertson, G.M. Rosair, A.J. Welch, Dalton Trans., 2011, 40, 7181.

M. Bakardjiev, J. Holub, M. J. Carr, J. D. Kennedy, B. Stibr, Dalton Trans., 2005, 909.

D. Kadlecek, A.M. Shedlow, S.O. Kang, P. J. Carroll, L.G. Sneddon, J. Am. Chem. Soc., 2003, 125, 212.

D.S. Perekalin, I.V. Glukhov, J. Holub, I. Císařova, B. Štíbr, A.R. Kudinov, Organometallics, 2008, 27, 5273–5278.

S.O. Kang, P.J. Carroll, L.G. Sneddon, Inorg. Chem. 1989, 28, 961.

M.T. Serrate, D. Ellis, G.M. Rosair, A.J. Welch, J. Organomet. Chem. 2013, 747, 211.

G.D. Friesen, A. Barriola, P. Daluga, P. Ragatz, J. C. Huffman, L.J. Todd, Inorg. Chem. 1980, 19, 458-466.

A.A.A. Attia, A. Lupan, R.B. King, Polyhedron, 2015, 85, 933-940

A. A. A. Attia, A. Lupan, R. B. King RSC Adv., 2016, 6, 1122-1128

A. Lupan, R.B. King, Polyhedron, 2014, 78, 130-134

D.S. Perekalin, I.V. Glukhov, J. Holub, I. Císařova, B. Štíbr, A.R. Kudinov, Organometallics, 2008, 27, 5273–5278.

A.A.A. Attia, A. Lupan, R.B. King, Polyhedron, 2016, in press

G.D. Friesen, A. Barriola, P. Daluga, P. Ragatz, J.C. Huffman,; L.J. Todd, Inorg. Chem., 1980, 19, 458-466.

A.A.A. Attia, A. Lupan, R.B. King, submitted.

Gaussian 09 (Revision A.02), Gaussian, Inc., Wallingford, CT, 2009.

STUDIA UBB CHEMIA, Volume 61 (LXI), No. 3, September 2016

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Published

2016-09-30

How to Cite

LUPAN, A. ., ATTIA, A. A. ., & KING, R. B. . (2016). THE EFFECT OF ELECTRON-RICH HETEROATOMS IN METALLABORANE CLUSTERS. Studia Universitatis Babeș-Bolyai Chemia, 61(3), 91–100. Retrieved from https://studia.reviste.ubbcluj.ro/index.php/chemia/article/view/8334

Issue

Volume 61, No. 3, Tome I, 2016

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Articles

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