INFLUENCE OF THICKNESS ON THE PROPERTIES OF TiO2 AND Ti(Nb)O2 THIN FILMS

Authors

Keywords:

metal oxides, titanium dioxide, thin films, thickness, solar cells applications

Abstract

Pure and Nb doped titanium dioxide films were grown by magnetron sputtering, for integration in hybrid polymer-semiconductor solar cells. The effect of the thickness of the films on their physical properties was investigated, emphasis given on the optical transparency, the surface morphology, the wettability and the conductivity. Particular surface parameters were determined and their variation with film thickness was investigated. Finally, a hydrophobic to hydrophilic transition under UV irradiation was studied.

References

B. Oregan and M. Gratzel, Nature, 1991, 353, 737.

U. Bach, D. Lupo, P. Comte, J.E. Moser, F. Weissortel, J. Salbeck, H. Spreitzer and M. Gratzel, Nature, 1998, 395, 583.

B.C. O’Regan, J.R. Durrant, P.M. Sommeling and N.J. Bakker, J. Phys. Chem. C, 2007, 111, 14001.

S.H. Park, A. Roy, S. Beaupre, S. Cho, N. Coates, J.S. Moon, D. Moses, M. Leclerc, K. Lee and A.J. Heeger, Nat. Photonics, 2009, 3, 297.

J.Y. Kim, S.H. Kim, H.H. Lee, K. Lee, W.L. Ma, X. Gong and A.J. Heeger, Adv. Mater., 2006, 18, 572.

A. Roy, S.H. Park, S. Cowan, M.H. Tong, S.N. Cho, K. Lee and A.J. Heeger, Appl. Phys. Lett., 2009, 95, 013302.

C. Waldauf, M. Morana, P. Denk, P. Schilinsky, K. Coakley, S.A. Choulis and C.J. Brabec, Appl. Phys. Lett., 2006, 89, 233517.

T. Kuwabara, T. Nakayama, K. Uozumi, T. Yamaguchi and K. Takahashi, Sol. Energy Mater. Sol. Cells, 2008, 92, 1476.

J. Yang, R. Zhu, Z.R. Hong, Y.J. He, A. Kumar, Y.F. Li and Y. Yang, Adv. Mater., 2011, 23, 3465.

L. Shen, G.H. Zhu, W.B. Guo, C. Tao, X.D. Zhang, C.X. Liu, W.Y. Chen, S.P. Ruan, Appl. Phys. Lett., 2008, 93, 073307.

S. Tepavcevic, S.B. Darling, N.M. Dimitrijevic, T. Rajh, S.J. Sibener, Small, 2009, 5, 1776.

K.J. Jiang, K. Manseki, Y.H. Yu, N. Masaki, K. Suzuki, Y.L. Song, S. Yanagida, Adv. Funct. Mater., 2009, 19, 2481.

Muktha, D. Mahanta, S. Patil, G. Madras, J. Solid State Chem., 2007, 180, 2986.

M. Mall, P. Kumar, S. Chand, L. Kumar, Chem. Phys. Lett., 2010, 495, 236.

R. Po, M. Maggini, N. Camaioni, J. Phys. Chem. C., 2010,114, 695.

N. Lu, S. Chen, H.T. Wang, X. Quan, H.M. Zhao, J. Solid State Chem., 2008, 181, 2852.

K. Palaniappan, J.W. Murphy, N. Khanam, J. Horvath, H. Alshareef, M. Quevedo-Lopez, M.C. Biewer, S.Y. Park, M.J. Kim, B.E. Gnade, M.C. Stefan, Macromolecules, 2009, 42, 3845.

X.X. Jiang, F. Chen, H. Xu, L.G. Yang, W.M. Qiu, M.M. Shi, M. Wang, Sol. Energy Mater. Sol. Cells, 2014, 94, 338.

J.A. Labastide, M. Baghgar, I. Dujovnet, Y. Yang, A.D. Dinsmore, B.G. Sumpter, D. Venkataramanm, M.D. Barnes, J. Phys. Chem. Lett., 2011, 2, 3085.

M. Krunks, A. Katerski, T. Dedova, I.O. Acik, A. Mere, Sol. Energy Mater. Sol. Cells, 2008, 92, 1016.

J.S. Kim, Y. Park, D.Y. Lee, J.H. Lee, J.H. Park, J.K. Kim, K. Cho, Adv. Funct. Mater., 2015, 20, 18.

Y.Y. Lin, T.H. Chu, C.W. Chen, W.F. Su, Appl. Phys. Lett., 2008, 92, 0533121.

G.K. Mor, S. Kim, M. Paulose, O.K. Karghese, K. Shankar, J. Bsaham, C.A. Grimes, Nano Lett., 2009, 9, 4250.

E.V. Buta, P. Pascariu, F. Prihor, L. Vlad, V. Pohoaţă, R. Apetrei, D. Luca, A. Nastută, I. Alupoaei, D. Mardare, Scientific Annals of “Alexandru Ioan Cuza din Iaşi” University, 2008, Tomul I, 4.

D. Wicaksana, A. Kobayashi, A. Kinbara, J. Vac. Sci. Technol. A, 1992, 10, 1479.

Downloads

Published

2016-03-30

Issue

Section

Articles

How to Cite

SUCHEA, M., VAMVAKAKI, M., LOULOUDAKIS, D., SIGALAS, M., KATSARAKIS, N., VERNARDOU, D., & KOUDOUMAS, E. (2016). INFLUENCE OF THICKNESS ON THE PROPERTIES OF TiO2 AND Ti(Nb)O2 THIN FILMS. Studia Universitatis Babeș-Bolyai Chemia, 61(1), 97-106. https://studia.reviste.ubbcluj.ro/index.php/chemia/article/view/8284