SYNTHESIS AND CHARACTERIZATION OF NOVEL GIOMERS FOR DENTAL APPLICATIONS

Ioana  HODISAN; Cristina  PREJMEREAN; Ioan  PETEAN; Doina  PRODAN; Tinca  BURUIANA; Loredana Elena COLCERIU; Lucian  BARBU-TUDORAN; Maria  TOMOAIA-COTISEL

doi:10.24193/subbchem.2017.4.12

SYNTHESIS AND CHARACTERIZATION OF NOVEL GIOMERS FOR DENTAL APPLICATIONS

Authors

Ioana HODISAN Raluca Ripan Institute for Research in Chemistry, Babes Bolyai University; Faculty of Dental Medicine, “Iuliu Haţieganu” University of Medicine and Pharmacy, Cluj-Napoca, Romania. Corresponding author: cristina.prejmerean@gmail.com.
Cristina PREJMEREAN Raluca Ripan Institute for Research in Chemistry, Babes Bolyai University, Cluj-Napoca, Romania. Email: cristina.prejmerean@gmail.com. https://orcid.org/0000-0002-6656-4234
Ioan PETEAN Research Center of Physical Chemistry, Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: ipetean@chem.ubbcluj.ro. https://orcid.org/0000-0003-3274-8817
Doina PRODAN Department of Polymer Composites, Raluca Ripan Institute for Research in Chemistry, Babes Bolyai University, Cluj-Napoca, Romania. Corresponding author: cristina.prejmerean@gmail.com. https://orcid.org/0000-0003-2467-2453
Tinca BURUIANA Petru Poni Institute of Macromolecular Chemistry, Iasi, Romania. Email: tbur@icmpp.ro.
Loredana Elena COLCERIU Faculty of Dental Medicine, “Iuliu Haţieganu” University of Medicine and Pharmacy, Cluj-Napoca, Romania. Email: loredana.colceriu@umfcluj.ro. https://orcid.org/0000-0002-9644-9747
Lucian BARBU-TUDORAN National Institute for Research and Development of Isotopic and Molecular Technologies, Cluj-Napoca, Romania. Email: lucian.barbu@itim-cj.ro. https://orcid.org/0000-0003-0360-016X
Maria TOMOAIA-COTISEL Research Center of Physical Chemistry, Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: maria.tomoaia@ubbcluj.ro. https://orcid.org/0000-0002-0995-3006

DOI:

https://doi.org/10.24193/subbchem.2017.4.12

Keywords:

dental giomers, adhesive system, microleakage, SEM, AFM

Abstract

The aim of the present work was to prepare and characterize a series of dental giomers and their corresponding dental adhesive and to evaluate the adhesion of the new materials at the restoration/tooth interface. The experimental giomers were prepared as monopastes by blending the resin matrices, a new pre-reacted glass, a radiopaque glass and fluorhydroxyapatite. The novelty of the work is represented by the using of a polyalkenoic acid based on acrylic acid, itaconic acid and N-acryloyl –L-leucine as the main component of the pre-reacted glass and of the primer in the adhesive system. In addition, the using of an original synthesized urethane tetra-methacrylate Bis-GMA analogue (Bis-GMAexp) as base monomer in the resin represents another element of novelty. The morphology of giomer samples was investigated by scanning electron microscopy. The sealing ability was tested by dye penetration method completed with atomic force microscopy investigation. The microleakage was evaluated using the score method. The results pointed out a remarkable dentin sealing for the new adhesive system and a strong adhesion at Bis-GMAexp-based giomer/ adhesive system/tooth interfaces in substantial agreement with very low value of microleakage.

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STUDIA UBB CHEMIA, Volume 62 (LXII), No. 4, Tome I, June 2017

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Published

2017-12-29

How to Cite

HODISAN, I. ., PREJMEREAN, C. ., PETEAN, I. ., PRODAN, D. ., BURUIANA, T. ., COLCERIU, L. E., … TOMOAIA-COTISEL, M. . (2017). SYNTHESIS AND CHARACTERIZATION OF NOVEL GIOMERS FOR DENTAL APPLICATIONS. Studia Universitatis Babeș-Bolyai Chemia, 62(4, Tome I), 143–154. https://doi.org/10.24193/subbchem.2017.4.12