SYNTHESIS, STRUCTURE AND LUMINESCENT PROPERTIES OF A MONONUCLEAR ZINC(II) COMPLEX WITH A BICOMPARTMENTAL LIGAND

Authors

  • Mihai RĂDUCĂ Department of Inorganic Chemistry, Faculty of Chemistry, University of Bucharest, Romania. Corresponding author: augustin.madalan@chimie.unibuc.ro. https://orcid.org/0000-0002-3996-6094
  • Augustin M. MĂDĂLAN Department of Inorganic Chemistry, Faculty of Chemistry, University of Bucharest, Romania. Email: augustin.madalan@chimie.unibuc.ro. https://orcid.org/0000-0002-2275-5004

DOI:

https://doi.org/10.24193/subbchem.2019.3.16

Keywords:

Zinc complexes, bicompartmental ligands, luminescence

Abstract

A mononuclear complex of Zn(II) with the Schiff base ligand derived from o-vanillin and 2,2-dimethyl-1,3-diaminopropane (H2valdmpn) was obtained and structurally characterized by X-ray diffraction on single crystal. In the [Zn(valdmpn)(H2O)] complex the metal ion is pentacoordinated with a square pyramidal geometry. The luminescent properties of the complex were investigated in solid state and solution following the influence of the solvent.

References

J. Wu; L. Zhao; P. Zhang; L. Zhang; M. Guo; J. Tang; Dalton Trans., 2015, 44, 11935-11942.

P. Cucos; F. Tuna; L. Sorace; I. Matei; C. Maxim; S. Shova; R. Gheorghe; A. Caneschi, M. Hillebrand; M. Andruh; Inorg. Chem., 2014, 53, 7738-7747.

D. Jiang; X. Yang; H. Chen; F. Wang; S. Wang; T. Zhu; L. Zhang; S. Huang; Dalton Trans., 2019, 48, 2206-2212.

G. Novitchi; J.-P. Costes, J.-P. Tuchagues; L. Vendier; W. Wernsdorfer; New J. Chem., 2008, 32, 197-200.

J.-P. Costes; F. Dahan; A. Dupuis; J.-P. Laurent; Inorg. Chem., 1996, 35 2400-2402.

M. Andruh; Chem. Commun., 2007, 2565-2577.

M. Andruh; Chem. Commun., 2011, 47, 3025-3042.

D.G. Branzea; A. Guerri; O. Fabelo; C. Ruiz-Pérez; L.-M. Chamoreau; C. Sangregorio; A. Caneschi; M. Andruh; Cryst. Growth Des., 2008, 8, 941-949.

D.G. Branzea; L. Sorace; C. Maxim; M. Andruh; A. Caneschi; Inorg. Chem., 2008, 47, 6590-6592.

M. Nayak; R. Koner; H.-H. Lin; U. Flörke; H.-H. Wei; S. Mohanta; Inorg. Chem., 2006, 45, 10764-10773.

S. Nastase; F. Tuna; C. Maxim; C.A. Muryn; N. Avarvari; R.E.P. Winpenny; M. Andruh; Cryst. Growth Des., 2007, 7, 1825-1831.

A.M. Madalan; N. Avarvari; M. Andruh; New J. Chem.; 2006, 30, 521-523.

A.M. Madalan; C.D. Ene; Inorg. Chim. Acta, 2018, 475, 184-192.

M. Nayak; S. Sarkar; P. Lemoine; S. Sasmal; R. Koner; H.A. Sparkes; J.A.K. Howard; S. Mohanta; Eur. J. Inorg. Chem., 2010, 744-752.

A. Cucos; A. Ursu; A.M. Madalan; C. Duhayon; J.-P. Sutter; M. Andruh; CrystEngComm, 2011, 13, 3756-3766.

T.D. Pasatoiu; C. Tiseanu; A.M. Madalan; B. Jurca; C. Duhayon; J.P. Sutter; M. Andruh; Inorg. Chem., 2011, 50, 5879-5889.

S.S. Sreejith; N. Mohan; M.R. Prathapachandra Kurup; Polyhedron, 2017, 135, 278-295.

Downloads

Published

2019-09-30

How to Cite

RĂDUCĂ, M. ., & MĂDĂLAN, A. M. . (2019). SYNTHESIS, STRUCTURE AND LUMINESCENT PROPERTIES OF A MONONUCLEAR ZINC(II) COMPLEX WITH A BICOMPARTMENTAL LIGAND. Studia Universitatis Babeș-Bolyai Chemia, 64(3), 193–202. https://doi.org/10.24193/subbchem.2019.3.16

Issue

Section

Articles

Similar Articles

<< < 1 2 3 4 5 6 > >> 

You may also start an advanced similarity search for this article.