SYNTHESIS AND CHARACTERIZATION OF FULLERENE-PYRIDYL ARENE RUTHENIUM COMPLEXES
Keywords:
fullerene; arene ligand; ruthenium; pyridyl ligand; half-sandwich complexesAbstract
Association of [60]fullerene with arene ruthenium moieties has been achieved for the first time. Two fullerenopyrrolidine derivatives (Npyr-C60) were synthesized via a 1,3-dipolar cycloaddition, and coordinated to arene ruthenium complexes to form two half-sandwich complexes of the general formula (p-cymene)RuCl2(Npyr-C60). The coordination of the fullerenopyrrolidines to the arene ruthenium unit was evidenced by NMR spectroscopy and mass spectrometry, thus confirming the formation of these novel arene ruthenium complexes.
References
J.L. Delgado, S. Filippone, F. Giacalone, M.Á. Herranz, B. Illescas, E.M. Pérez, N. Martín, Topics in Current Chemistry, 2014, 350, 1.
(a) H.W. Kroto, J.R. Heath, S.C. OʼBrien, R.F. Curl, R.E. Smalley, Nature, 1985, 318, 162. (b) R.C. Haddon, L.E. Brus, K. Raghavachari, Chemical Physics Letters, 1986, 125, 459. (c) R.C. Haddon, Journal of the American Chemical Society, 1997, 119, 1797. (d) A. Hirsch, “Principles of Fullerene Reactivity”, Vol. 199, Springer, Berlin, 1999. (e) N. Martín, Chemical Communications, 2013, 49, 1039.
(a) C. Bingel, Chemische Berichte, 1993, 126, 1957. (b) M. Maggini, G. Scorrano, M. Prato, Journal of the American Chemical Society, 1993, 115, 9798. (c) M. Prato, M. Maggini, Accounts of Chemical Research, 1998, 31, 519. (d) K. Kordatos, T. Da Ros, S. Bosi, E. Vázquez, M. Bergamin, C. Cusan, F. Pellarini, V. Tomberli, B. Baiti, D. Pantarotto, V. Georgakilas, G. Spalluto, M. Prato, Journal of Organic Chemistry, 2001, 66, 4915.
(a) D.M. Guldi, Chemical Society Reviews, 2002, 31, 22. (b) M. Sawamura, Y. Kuninobu, M. Toganoh, Y. Matsuo, M. Yamanaka, E. Nakamura, Journal of the American Chemical Society, 2002, 124, 9354. (c) M. Segura, L. Sánchez, J. de Mendoza, N. Martín, D.M. Guldi, Journal of the American Chemical Society, 2003, 125, 15093. (d) D.M. Guldi, G.M. Aminur Rahman, V. Sgobba, C. Ehli, Chemical Society Reviews, 2006, 35, 471.
(a) B.C. Thompson, J.M.J. Fréchet, Angewandte Chemie International Edition, 2008, 47, 58. (b) C.J. Brabec, S. Gowrisanker, J.J.M. Halls, D. Laird, S. Jia, S.P. Williams, Advanced Materials, 2010, 22, 3839.
(a) M. Maggini, A. Donò, G. Scorranoa, M. Prato, Journal of the Chemical Society; Chemical Communications, 1995, 846. (b) N. Armaroli, C. Boudon, D. Felder, J.-P. Gisselbrecht, M. Gross, G. Marconi, J.-F. Nicoud, J.-F. Nierengarten, V. Vicinelli, Angewandte Chemie International Edition, 1999, 38, 3730. (c) K. Barthelmes, J. Kübel, A. Winter, M. Wächtler, C. Friebe, B. Dietzek, U.S. Schubert, Inorganic Chemistry, 2015, 54, 3159.
F. Cardinali, J.-L. Gallani, S. Schergna, M. Maggini, J.-F. Nierengarten, Tetrahedron Letters, 2005, 46, 2969.
(a) Y. Matsuo, E. Nakamura, Organometallics, 2003, 22, 2554. (b) C.-H. Chen, C.-S. Chen, H.-F. Dai, W.-Y. Yeh, Dalton Transactions, 2012, 41, 3030. (c) F.L. Bowles, M.M. Olmstead, A.L. Balch, Journal of the American Chemical Society, 2014, 136, 3338. (d) W.-Y. Yeh, Journal of Organometallic Chemistry, 2014, 751, 351. (e) C.-H. Chen, A. Aghabali, C. Suarez, M.M. Olmstead, A.L. Balch, L. Echegoyen, Chemical Communications, 2015, 51, 6489.
B. Therrien, Coordination Chemistry Reviews, 2009, 253, 493. (b) A.K. Singh, D.S. Pandey, Q. Xu, P. Braunstein, Coordination Chemistry Reviews, 2014, 270-271, 31.
(a) K. Severin, Chemical Communications, 2006, 3859. (b) B. Therrien, European Journal of Inorganic Chemistry, 2009, 2445.
(a) A.F.A. Peacock, P.J. Sadler, Chemistry: An Asian Journal, 2008, 3, 1890. (b) G. Süss-Fink, Dalton Transactions, 2010, 39, 1673. (c) G.S. Smith, B. Therrien, Dalton Transactions, 2011, 40, 10793. (d) T.R. Cook, V. Vajpayee, M.H. Lee,
P.J. Stang, K.-W. Chi, Accounts of Chemical Research, 2013, 46, 2464. (e) A.A. Nazarov, C.G. Hartinger, P.J. Dyson, Journal of Organometallic Chemistry, 2014, 751, 251.
(a) L. Delaude, A. Demonceau, Dalton Transactions, 2012, 41, 9257. (b) A.L. Noffke, A. Habtemariam, A.M. Pizarro, P.J. Sadler, Chemical Communications, 2012, 48, 5219. (c) G. Süss-Fink, Journal of Organometallic Chemistry, 2014, 751, 2. (d) P. Kumar, R.K. Gupta, D.S. Pandey, Chemical Society Reviews, 2014, 43, 707.
A. Pitto-Barry, N.P.E. Barry, V. Russo, B. Heinrich, B. Donnio, B. Therrien, R. Deschenaux, Journal of the American Chemical Society, 2014, 136, 17616.
G. Porzi, S. Sandri, Tetrahedron: Asymmetry, 1996, 7, 189.
(a) C.-H. Andersson, G. Berggren, S. Ott, H. Grennberg, European Journal of Inorganic Chemistry, 2011, 1744. (b) C.-H. Andersson, L. Nyholm, H. Grennberg, Dalton Transactions, 2012, 41, 2374. (c) B. Jin, J. Shen, R. Peng, C. Chen, S. Chu, European Journal of Organic Chemistry, 2014, 6252. (d) A. Parveen, V. Sughanya, S. Nagarajan, RSC Advances, 2015, 5, 20351.
(a) P. Govender, N.C. Antonels, J. Mattsson, A.K. Renfrew, P.J. Dyson, J.R. Moss,
B. Therrien, G.S. Smith, Journal of Organometallic Chemistry, 2009, 694, 3470. (b) N.P.E. Barry, M. Austeri, J. Lacour, B. Therrien, Organometallics, 2009, 28, 4894. (c) O. Zava, J. Mattsson, B. Therrien, P.J. Dyson, Chemistry: A European Journal, 2010, 16, 1428. (d) N.P.E. Barry, F. Edafe, B. Therrien, Dalton Transactions, 2011, 40, 7172.
(a) T.-T. Thai, B. Therrien, G. Süss-Fink, Journal of Organometallic Chemistry, 2009, 694, 3973. (b) M. Auzias, J. Gueniat, B. Therrien, G. Süss-Fink, A.K. Renfrew, P.J. Dyson, Journal of Organometallic Chemistry, 2009, 694, 855. (c) M. Gras,
B. Therrien, G. Süss-Fink, A. Casini, F. Edafe, P.J. Dyson, Journal of Organometallic Chemistry, 2010, 695, 1119.
P. Govindaswamy, B. Therrien, G. Süss-Fink, P. Štěpnička, J. Ludvík, Journal of Organometallic Chemistry, 2007, 692, 1661.
M.A. Bennett, T.-N. Huang, T.W. Matheson, A.K. Smith, Inorganic Syntheses, 1982, 21, 74.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2015 Studia Universitatis Babeș-Bolyai Chemia
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
