Study of Kazakhstan’s Shungite as Electrocatalyst Substrate in Hydrogen Evolution Reaction in Acidic Media

Authors

  • Azhar Farooq ATCHABAROVA Center of Physical Chemical Methods of Research and Analysis, Al-Farabi Kazakh National University, Almaty, Kazakhstan. https://orcid.org/0000-0002-4600-2728
  • Dinara ABDUAKHYTOVA Center of Physical Chemical Methods of Research and Analysis, Al-Farabi Kazakh National University, Almaty, Kazakhstan. https://orcid.org/0000-0002-4316-0755
  • Khaisa AVCHUKIR Center of Physical Chemical Methods of Research and Analysis, Al-Farabi Kazakh National University, Almaty, Kazakhstan. https://orcid.org/0000-0001-6612-0775
  • Graziella Liana TURDEAN Research Center of Electrochemistry and Non-Conventional Materials, Faculty of Chemistry and Chemical Engineering; Interdisciplinary Research Institute on Bio-Nano-Sciences, Cluj-Napoca, Romania. *Corresponding authors: abduakhytova@mail.ru, graziella.turdean@ubbcluj.ro https://orcid.org/0000-0003-1273-6878
  • Saken ABDIMOMYN Center of Physical Chemical Methods of Research and Analysis, Al-Farabi Kazakh National University, Almaty, Kazakhstan. https://orcid.org/0000-0002-5985-9050
  • Rustam TOKPAYEV Center of Physical Chemical Methods of Research and Analysis, Al-Farabi Kazakh National University, Almaty, Kazakhstan. https://orcid.org/0000-0002-0117-4454
  • Tamina KHAVAZA Center of Physical Chemical Methods of Research and Analysis, Al-Farabi Kazakh National University, Almaty, Kazakhstan. https://orcid.org/0000-0002-1614-3060
  • Mikhail NAURYZBAYEV Center of Physical Chemical Methods of Research and Analysis, Al-Farabi Kazakh National University, Almaty, Kazakhstan. https://orcid.org/0000-0002-6781-6464

DOI:

https://doi.org/10.24193/subbchem.2024.3.02

Keywords:

hydrogen, carbon material, shungite, electrocatalyst, hydrogen evolution reaction

Abstract

The most efficient method to produce hydrogen is by electrolysis of water, and scientist’s current research is focused on developing inexpensive catalysts for this process. The article aims to study a carbon material (CM) obtained from shungite raw materials as electrocatalyst support in hydrogen evolution reaction (HER). The obtained activated CM has a multi-layered lamellar morphology with a specific surface area 356.40 m2/g. Electrocatalytical properties of the activated carbon material are the following: overpotential (η) at 10 mА/cm2 of 0.515 V vs. RHE with a Tafel slope of 172.5 mV/dec and good stability in acidic media. The obtained results show that activated CM from shungite raw material can be used as an electrocatalyst for obtaining hydrogen.

References

M. Sastri; Int. J. Hydrogen Energy, 1980, 5, 365 – 367. doi:10.1016/0360-3199(80)90017-8.

L. Tianze; D. Yuanyuan; Zh. Jianjiao; W. Lixue; D. Fangzheng; W. Dandan; Z. Hong; Int. J. Hydrogen Energy, 2024, 77, 359 – 372.

doi:10.1016/j.ijhydene.2024.06.185.

H.-E. Cheng; W.-L. Li; Z.-P. Yang; Int. J. Hydrogen Energy, 2019, 44, 30141 – 30150. doi:10.1016/j.ijhydene.2019.09.188.

M. Molla; M. Sarker; A. Kibria; Bangladesh J. Sci. Ind. Res., 2008, 43, 103 – 116. doi:10.3329/bjsir.v43i1.861.

Z. Wang; X. Ren; Y. Luo; L. Wang; G. Cui; F. Xie; X. Sun; Nanoscale, 2018, 10, 12302 – 12307. doi:10.1039/c8nr02071j.

J. Benson; M. Li; S. Wang; P. Wang; P. Papakonstantinou; ACS Appl. Mater. Interfaces, 2015, 7, 14113 – 14122. doi:10.1021/acsami.5b03399.

X. Qian; T. Hang; S. Shanmugam; M. Li; ACS Appl. Mater. Interfaces, 2015, 7, 15716 – 15725. doi:10.1021/acsami.5b00679.

V. Vij; S. Sultan; A. M. Harzandi; A. Meena; J. N. Tiwari; W.-G. Lee; K. S. Kim; ACS Catalysis, 2017, 7, 7196 – 7225. doi:10.1021/acscatal.7b01800.

C. Lo Vecchio; A. S. Arico; G. Monforte; V. Baglio; Renew. Energy, 2018, 120, 342 – 349. doi:10.1016/j.renene.2017.12.084.

J. Zhang; Z. Xia; L. Dai; Science Adv., 2015, 1, e1500564. doi:10.1126/sciadv.1500564.

R. Paul; Q. Dai; C. Hu; L. Dai; Carbon Energy, 2019, 1, 19 – 31. doi:10.1002/cey2.5.

S. A. Efremov; Production technology of carbon-mineral materials on the basis of shungite rocks: PhD thesis, 05.17.01, Almaty, 2010, p. 240.

B. E. Conway; B. V. Tilak; Electrochim Acta, 2002, 47, 3571 – 3594. doi: 10.1016/S0013-4686(02)00329-8.

T. Shinagawa; A. T. Garcia-Esparza; K. Takanabe; Scientific Rep, 2015, 5, 13801. doi: 10.1038/srep13801.

F. Bao; E. Kemppainen; I. Dorbandt; R. Bors; F. Xi; R. Schlatmann; R. van de Krol; S. Calnan; ChemElectroChem 2021, 8, 195 – 208. doi: 10.1002/celc.202001436.

H. Prats; K. Chan; Phys. Chem. Chem. Phys., 2021, 23, 27150 – 27158. doi: 10.1039/d1cp04134g.

R. S. A. Saravanan; N. Prabu; M. Sasidharan; G. Maduraiveeran; Appl. Surf. Sci., 2019, 489, 725 – 733. doi:10.1016/japsusc.2019.06.040.

Y. Zheng; Y. Jiao; L. H. Li; T. Xing; Y. Chen; M. Jaroniec; S. Z. Qiao; ACS Nano, 2014, 8, 5290 – 5296. doi: 10.1021/nn501434a.

Downloads

Published

2024-09-30

How to Cite

ATCHABAROVA, A. F., ABDUAKHYTOVA, D., AVCHUKIR, K., TURDEAN, G. L., ABDIMOMYN, S., TOKPAYEV, R., … NAURYZBAYEV, M. (2024). Study of Kazakhstan’s Shungite as Electrocatalyst Substrate in Hydrogen Evolution Reaction in Acidic Media. Studia Universitatis Babeș-Bolyai Chemia, 69(3), 25–34. https://doi.org/10.24193/subbchem.2024.3.02

Issue

Section

Articles

Most read articles by the same author(s)

1 2 > >> 

Similar Articles

<< < 18 19 20 21 22 23 24 > >> 

You may also start an advanced similarity search for this article.