SYNTHESIS AND ELECTRONIC PROPERTIES OF 3-ARYL 10H-PHENOTHIAZINES

Authors

  • Christa S. BARKSCHAT Organisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Germany. Corresponding author: ThomasJJ.Mueller@hhu.de.
  • Thomas J. J. MÜLLER Institut für Organische Chemie und Makromolekulare Chemie, Heinrich-Heine-Universität Düsseldorf, Germany. Email: ThomasJJ.Mueller@hhu.de. https://orcid.org/0000-0001-9809-724X

Keywords:

Cross-coupling – DFT calculations – Heterocycles – Substituent Effects – UV/Vis Spectroscopy

Abstract

3-Bromo 10H-phenothiazines, even the 10H-unsubstituted derivative, can be efficiently coupled with several boronic acids to give 3-aryl 10H-phenothiazines with good to excellent yields. Selected electronic properties (UV/Vis spectroscopy, cyclic voltammetry, DFT calculations) are discussed and correlations of the Hammett-Taft substituent parameters are established for rationalizing the transmission of the remote electronic substituent effects.

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Published

2016-09-30

How to Cite

BARKSCHAT, C. S. ., & MÜLLER, T. J. J. . (2016). SYNTHESIS AND ELECTRONIC PROPERTIES OF 3-ARYL 10H-PHENOTHIAZINES. Studia Universitatis Babeș-Bolyai Chemia, 61(3), 55–72. Retrieved from https://studia.reviste.ubbcluj.ro/index.php/chemia/article/view/8331

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