THE AGGREGATION BEHAVIOR OF AN A3B FREE BASE PORPHYRIN AND ITS APPLICATION AS THE AGGREGATION BEHAVIOR OF AN A3B FREE BASE PORPHYRIN AND ITS APPLICATION AS CHROMIUM(III)-SELECTIVE MEMBRANE SENSORCHROMIUM(III)-SELECTIVE MEMBRANE SENSOR
Keywords:
membrane carrier, A3B porphyrin, aggregation behavior, electron tomographyAbstract
A polyvinyl chloride membrane chromium(III)-selective electrode based on a synthesized A3B free base porphyrin, namely 5-(4-pyridyl)-10,15, 20-tris(phenoxy-phenyl)porphyrin, as membrane carrier was formulated and evaluated. The electrode exhibits a near-Nernstian response over the chromium(III) concentration range of 3x10−5 ÷ 1x10−1 M and shows good selectivity with respect to a wide range of cations. The aggregation behavior of the porphyrin macrocycle was investigated using TEM and STEM analytic techniques and revealed the formation of different shapes of nanostructures. Electron tomography was also employed in the study of the porphyrin aggregates.
References
D.E. Kimbrough, Y. Cohen, A.M. Winer, L. Creelman, C.A. Mabuni, Critical Reviews in Environmental Science and Technology, 1999, 29, 1.
McGraw-Hill, “Concise Encyclopedia of Science and Technology”, 5th edition, McGraw-Hill, New York, 2004.
H.A. Zamani, M.R. Ganjali, M.R. Abedi, P. Norouzi, Sensor Letters, 2007, 5, 1.
R.K. Sharma, A. Goel, Analytica Chimica Acta, 2005, 534, 137.
Y. Masuda, E. Ishida, K. Hiraga, Nippon Kagaku Kaishi, 1980, 10, 1453.
S.S.M. Hassan, M.N. Abbas, G.A.E. Moustafa, Talanta, 1996, 43, 797.
A.K. Singh, A. Panwar, S. Kumar, S. Baniwal, Analyst, 1999, 124, 521.
A. Abbaspour, A. Izadyar, Talanta, 2001, 53, 1009.
T.V. Velikanova, A.N. Titov, M.A. Malkova, Journal of Analytical Chemistry, 2001, 56, 666.
M.B. Gholivand, F. Sharifpour, Talanta, 2003, 60, 707.
A. Sil, V. S. Ijeri, A.K. Srivastava, Analytical and Bioanalytical Chemistry, 2004, 378, 1666.
A.K. Singh, R. Singh, P. Saxena, Sensors, 2004, 4, 187.
M.R. Ganjali, P. Norouzi, F. Faridbod, M. Ghorbani, M. Adib, Analytica Chimica Acta, 2006, 569, 35.
V.K. Gupta, A.K. Jain, P. Kumar, S. Agarwal, G. Maheshwari, Sensors and Actuators B, 2006, 113, 182.
M. Kia, H. Aghaie, M. Arvand, K. Zare, M. Aghaie, Journal of Physical & Theoretical Chemistry Islamic Azad University of Iran, 2006, 3, 105.
H.A. Zamani, G. Rajabzadeh, M.R. Ganjali, Sensors and Actuators B, 2006, 119, 41.
H.A. Zamani, G. Rajabzadeh, M. Masrornia, A. Dejbord, M.R. Ganjali, N. Seifi, Desalination, 2009, 249, 560.
H.A. Zamani, S. Sahebnasagh, International Journal of Electrochemical Science, 2013, 8, 3708.
V.K. Gupta, A.K. Jain, Z. Ishtaiwi, H. Lang, G. Maheshwari, Talanta, 2007, 73, 803.
D. Vlascici, E. Fagadar-Cosma, I. Popa, V. Chiriac, M. Gil-Agusti, Sensors, 2012, 12, 8193.
D. Vlascici, I. Popa, V.A. Chiriac, G. Fagadar-Cosma, H. Popovici, E. Fagadar-Cosma, Chemistry Central Journal, 2013, 7, 111.
V. Snitka, M. Rackaitis, R. Rdaite, Sensors and Actuators B, 2005, 109, 159.
Q. Liu, Y. Yang, H. Li, R. Zhu, Q. Shao, S. Yang, J. Xu, Biosensors and Bioelectronics, 2015, 64, 147.
L. Yang, N. Larouche, R. Chenitz, G. Zhang, M. Lefevre, J.P. Dodelet, Electrochimica Acta, 2015, 159, 184.
P.A. Midgley, R. Dunin-Borkowski, Nature Materials, 2009, 8, 271.
G.S. Liu, S.D. House, J. Kacher, M. Tanaka, K. Higashida, I. M. Robertson, Materials Characterization, 2014, 87, 1.
T. Djuric, T. Ules, S. Gusenleitner, N. Kayunkid, H. Plank, G. Hlawacek, C. Teichert, M. Brinkmann, M. Ramsey, R. Resel, Physical Chemistry Chemical Physics, 2012, 14, 262.
H.H. Mezerji, W.V. den Broek, S. Bals, Ultramicroscopy, 2011, 111, 330.
E. Fagadar-Cosma, G. Fagadar-Cosma, M. Vasile, C. Enache, Current Organic Chemistry, 2012, 16, 931.
Y. Umezawa, P. Buhlmann, K. Umezawa, K. Tohda, Pure and Applied Chemistry, 2000, 72, 1851.
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