INVESTIGATION OF SYNERGIC/ANTI-SYNERGIC INTERACTIONS OF DIHYDROXIFUMARIC ACID AND ASCORBIC ACID WITH DPPH
DOI:
https://doi.org/10.24193/subbchem.2021.2.04Keywords:
dihydroxyfumaric acid, ascorbic acid, DPPH, wine matrix, stopped-flow.Abstract
Reaction of the free-radical 2,2-diphenyl-1-picrylhydrazyl (DPPH) with dihydroxyfumaric acid (DHF) and ascorbic acid (AA) was investigated in ethanolic media and in wine simulated matrix by using a stopped-flow system. The antioxidant activity for both acids were significantly higher in wine matrix, the observed constants (kobs) being about 3 s-1 for DHF and 0.66 s-1 for AA. Synergic and anti-synergic interactions of DHF and AA against DPPH were also investigated. A strong anti-synergic effect was noticed in ethanol (kobs < 0.35 s-1). In wine simulated matrix the constants were higher than in ethanol (kobs ≈ 1 s-1), but still too small for a synergic effect. Some explanations concerning the mechanisms of antioxidant action are proposed.
References
H.J.H. Fenton; J. Chem. Soc. Trans., 1894, 65, 899–910.
A.C. Clark; Eur. Food Res. Technol., 2008, 226, 925–931.
L. Hough; J.K.N. Jones; Nature, 1951, 167, 180–183.
A. Eschenmoser; Chem. Biodivers., 2007, 4, 554–573.
V. Naidu Sagi; P. Karri; F. Hu; R. Krishnamurthy; Angew. Chemie, 2011, 123, 8277–8280.
N. Secara; G. Duca; L. Vlad; F. Macaev; Chem. J. Mold., 2011, 6, 29-44.
B. García; R. Ruiz; J.M. Leal; J. Phys. Chem., 2008, 112, 4921–4928.
L. Vacarciuc; Agricultura, 2008, 57, 1–8.
G. Badea; A. Antoce; Sci. Pap. B, Hortic., 2015, 59, 123–140.
C. Vicol; G. Duca; Rev. Şt., Inov., Cult. Art. „Akademos”, 2020, 56, 39–43.
R. Lo Scalzo; Food Chem.,2008, 107, 40–43.
W. Piang-Siong; P. De Caro; A. Marvilliers; X. Chasseray; B. Payet; A.S.C. Sing; B. Illien; Food Chem., 2017, 214, 447–452.
P.R. Quiroga; V. Nepote; M.T. Baumgartner; Food Chem., 2019, 277, 267–272.
S. Motta; M. Guaita; C. Cassino; A. Bosso; Food Chem., 2020, 313, 126045.
C. Dallas; J.M. Ricardo-da-Silva; O. Laureano; J. Agric. Food Chem., 1996, 44, 2402–2407.
P. Comuzzo; F. Battistutta; M. Vendrame; M.S. Páez; G. Luisi; R. Zironi; Food Chem., 2015, 168, 107–114.
O. Friaa; D. Brault; Org. Biomol. Chem., 2006, 4, 2417–2423.
J.M. Sendra; E. Sentandreu; J.L. Navarro; Eur. Food Res. Technol., 2006, 223, 615–624.
D. Villaño; M.S. Fernández-Pachón; M. L. Moyá; A.M. Troncoso; M. C. García-Parrilla; Talanta, 2007, 71, 230–235.
N. Secara; Chem. J. Mold., 2010, 5, 83–87.
M. Foti; C. Daquino; C. Geraci; J. Org. Chem, 2004, 14, 2309–2314.
U. Cornelli; Clin. Dermatol., 2009, 27, 175–194.
R. Tsao; Handbook of antioxidants for food preservation, Woodhead Publishing, 2015, pp. 335-347.
B.L. Freeman; D.L. Eggett; T.L. Parker; J. Food Sci., 2010, 75, 570–576.
M.N. Peyrat-Maillard; M.E. Cuvelier; C. Berset; J. Am. Oil Chem. Soc., 2003, 80, 1007–1012.
P. Pedrielli; L.H. Skibsted; J. Agric. Food Chem., 2002, 50, 7138–7144.
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