LEAD-CADMIUM IONS RECUPERATIVE SEPARATION BY CHITOSAN–sEPDM–POLYPROPYLENE HOLLOW FIBER COMPOSITE MEMBRANES

Alexandru  GORAN; Hussam Nadum Abdalraheem  AL-ANI; Alexandra-Raluca  GROSU; Geani Teodor  MAN; Vlad-Alexandru  GROSU; Aurelia Cristina  NECHIFOR

doi:10.24193/subbchem.2023.2.13

Authors

Alexandru GORAN Analytical Chemistry and Environmental Engineering Department, Politehnica University, Bucharest, Romania. Email: alexandru@santego.ro. https://orcid.org/0000-0003-3316-3482
Hussam Nadum Abdalraheem AL-ANI Analytical Chemistry and Environmental Engineering Department, Politehnica University, Bucharest, Romania; Chemical Industries Department, Institute of Technology, Middle Technical University, Al Zafaraniyah, Baghdad, Iraq. Email: hussamalani32@gmail.com. https://orcid.org/0000-0001-9056-9185
Alexandra-Raluca GROSU Analytical Chemistry and Environmental Engineering Department, Politehnica University, Bucharest, Romania. Email: andra.grosu@upb.ro. https://orcid.org/0000-0002-6271-6456
Geani Teodor MAN Analytical Chemistry and Environmental Engineering Department, Politehnica University, Bucharest; National Research and Development Institute for Cryogenics and Isotopic Technologies-ICSI, Râmnicu Vâlcea, Romania. Email: man_geani@yahoo.com. https://orcid.org/0000-0002-8667-3446
Vlad-Alexandru GROSU Department of Electronic Technology and Reliability, Faculty of Electronics, Telecommunications and Information Technology, Politehnica University, Bucharest, Romania. Email: vlad.grosu@upb.ro. https://orcid.org/0000-0002-4263-7048
Aurelia Cristina NECHIFOR Analytical Chemistry and Environmental Engineering Department, Politehnica University, Bucharest, Romania. Email: aurelia.nechifor@upb.ro. https://orcid.org/0000-0001-8891-8948

DOI:

https://doi.org/10.24193/subbchem.2023.2.13

Keywords:

membranes, composite membranes, chitosan, sEPDM, hollow fiber, cadmium separation, lead separation

Abstract

Although batteries containing heavy metals and toxic chemicals, including lead and cadmium, are supposed to be selectively collected, they still end up on municipal waste processing platforms. The separation of cadmium and lead ions is a problem that is circumscribed to the development of urban mining. This paper presents the recuperative separation of lead and cadmium ions by a composite membrane based on chitosan (Chi), sulfonated ethylene–propylene–diene terpolymer (sEPDM), and polypropylene hollow fiber (PPyHF). The performances of selected membranes are presented comparatively, both from the point of view of the morpho-structural characteristics, as well as of the performances in the target ion separation process, with recently reported results obtained with composite membranes based on chitosan.

References

V. Rai; D. Liu; D. Xia; Y. Jayaraman; J.-C.P. Gabriel; Recycling, 2021, 6, 53.

A. Khaliq; M.A. Rhamdhani; G. Brooks; S. Masood; Resources, 2014, 3, 152-179.

Y. Zhao; O. Pohl; A.I. Bhatt; G.E. Collis; P.J. Mahon; T. Rüther; A.F. Hollenkamp; Sustain. Chem., 2021, 2, 167-205.

F.M. Păncescu; A. Ferencz (Dinu); V.A. Grosu; A. Goran; G. Nechifor; U.P.B. Sci. Bull., Series B, 2023, 85 (1), 77-88.

A.E. Kostanyan; V.V.Belova; Y.A. Zakhodyaeva; A.A. Voshkin; Membranes, 2023, 13, 418.

J.M. Carretas; L.M. Ferreira; P.M.P. Santos; S.S. Gomes; M.F. Araújo; L. Maria; J.P. Leal; Membranes, 2023, 13, 467.

S. Koter; P. Szczepański; M. Mateescu; G. Nechifor; L. Badalau; I. Koter, Sep. Purif. Technol., 2013, 107, 135-143.

K. Filipowiak; P. Dudzińska; K. Wieszczycka; T. Buchwald; M. Nowicki; A. Lewandowska; A. Marcinkowska; Materials, 2021, 14, 5008.

K. Witt; W. Urbaniak; M.A. Kaczorowska; D. Bożejewicz; Polymers, 2021, 13, 1454.

I.M. Nafliu; H.N.A. Al-Ani; A.R. Grosu (Miron); P.C. Albu; G. Nechifor; Mat. Plast., 2019, 1, 32–36.

S. Yuan; J. Wang; X. Wang; S. Long; G. Zhang; J. Yang; Polym. Eng. Sci., 2015, 55, 2829–2837.

A.R. Grosu; I.M. Nafliu; I.S. Din; A.M. Cimbru; G. Nechifor; UPB Sci. Bull. Ser. B Chem. Mater. Sci., 2020, 82, 25–34.

E. Radzyminska-Lenarcik; I. Pyszka; A. Kosciuszko; Materials, 2021, 14, 4436.

A.C. Nechifor; S. Cotorcea; C. Bungău; P.C. Albu; D. Pașcu; O. Oprea; A.R. Grosu; A. Pîrțac; G. Nechifor; Membranes, 2021, 11, 256.

M.-W. Wan; C.-C. Kan; B.D. Rogel; M.L.P. Dalida; Carbohydr. Polym., 2010, 80, 891–899.

Z. Yang; Y. Chai; L. Zeng; Z. Gao; J. Zhang; H. Ji; Molecules, 2019, 24, 4205.

M.F. Hamza; Y. Wei; H.I. Mira; A.A.H. Abdel-Rahman; E. Guibal; Chem. Eng. J., 2019, 362, 310–324.

F. Wang; L.J. Wang; J.S. Li; X.Y. Sun; W.Q. Han; Trans. NonFerr. Met. Soc. China, 2009, 19, 740–744.

A. Demirbas; E. Pehlivan; F. Gode; T. Altun; G. Arslan; J. Colloid Interface Sci., 2005, 282, 20–25.

A.C. Nechifor; A. Pîrțac; P.C. Albu; A.R. Grosu; F. Dumitru; I.A; Dimulescu (Nica); O. Oprea; D. Pașcu; G. Nechifor; S.G. Bungău; Membranes, 2021, 11, 429.

I.A. Dimulescu; A.C. Nechifor; C. Bǎrdacă; O. Oprea; D. Paşcu; E.E. Totu; P.C. Albu; G. Nechifor; S.G. Bungău; Nanomaterials, 2021, 11, 1204.

A.C. Nechifor, A. Goran; V.-A. Grosu; C. Bungău; P.C. Albu; A.R. Grosu; O. Oprea; F.M.Păncescu; G. Nechifor; Membranes, 2021, 11, 445.

Naida S. Gill; F. B. Taylor; W. E. Hatfield; W. E. Parker; Carol S. Fountain; Fred L. Bunger; Tetrahalo Complexes of Dipositive Metals in the First Transition Series, in Inorganic Syntheses., 1967, 9, 136–142.

K.C. Liddell; R.G. Bautista; Hydrometallurgy, 1988, 21(1), 113-124.

P. Szczepański; H. Guo; K. Dzieszkowski; Z. Rafiński; A. Wolan; K. Fatyeyeva; J. Kujawa; W. Kujawski; J.Membr. Sci., 2021, 638, 119674.

A.M. Cimbru; A.A.K.K. Rikabi; O. Oprea; A.R. Grosu; S.-K. Tanczos; M.C. Simonescu; D. Pașcu; V.-A. Grosu; F. Dumitru; G. Nechifor; Membranes, 2022, 12, 833.

I.S. Din; A.M. Cimbru; A.A.K.K. Rikabi; S.K. Tanczos; S. Ticu (Cotorcea); G. Nechifor; Rev. Chim. (Bucharest), 2018, 69(7), 1603-1607.

M. Ghimpusan; G. Nechifor; A.C. Nechifor; S.O. Dima; P. Passeri; J. Environ. Manag. 2017, 203, 811–816.

P. Szczepański; Membranes 2023, 13, 236.

V.A. Fedorov; M.A. Kuznechikhina; I.V. Kanarsh; G.M. Kirnyuk; G.E. Chernikova; Sov. J. Coord. Chem., 1978, 4, 33–38.

K.S. Rao, G.R. Chaudhury, B.K. Mishra, Resin. Int. J. Miner. Process., 2010, 97, 68–73.