EFFECT OF TRACE SILICON ON THE PROPERTIES OF IRON-BASED HETEROGENEOUS FENTON CATALYSTS

Authors

  • Jianjun ZHAO Bengbu University, School of Materials and Chemical Engineering, Bengbu, 233030 China. *Corresponding author: zjj@bbc.edu.cn https://orcid.org/0000-0002-1042-3360
  • Yan SHU Bengbu University, School of Materials and Chemical Engineering, Bengbu, 233030 China
  • Leifeng JIA General Water of China (Bengbu) Co., LTD, Bengbu, 233000 China
  • Xianfeng ZHANG Bengbu University, School of Materials and Chemical Engineering, Bengbu, 233030 China
  • Muxin LIU Bengbu University, School of Materials and Chemical Engineering, Bengbu, 233030 China
  • Xu LI Bengbu University, School of Materials and Chemical Engineering, Bengbu, 233030 China
  • Anping XU Bengbu University, School of Materials and Chemical Engineering, Bengbu, 233030 China
  • Xiaoxuan ZHANG Bengbu University, School of Materials and Chemical Engineering, Bengbu, 233030 China
  • Jing YE Bengbu University, School of Materials and Chemical Engineering, Bengbu, 233030 China
  • Ran RONG Bengbu University, School of Materials and Chemical Engineering, Bengbu, 233030 China
  • Jiatong HAN Bengbu University, School of Materials and Chemical Engineering, Bengbu, 233030 China
  • Shenghao LIAO Bengbu University, School of Materials and Chemical Engineering, Bengbu, 233030 China

DOI:

https://doi.org/10.24193/subbchem.2026.2.09

Keywords:

heterogeneous Fenton catalyst, trace Si modification, highly dispersed active components, acid-base properties of catalyst

Abstract

It is an important task for modifying heterogeneous Fenton catalysts to effectively degrade organic pollutants in water. Most studies have modified heterogeneous Fenton catalysts through addition of other metal active species. Here, a series of Si-Fe/γ-Al2O3 (x, x = Si/Fe mass ratio per gram of support) catalysts were prepared via wet impregnation method, and the characterization results show that the addition of trace Si (x < 0.10) facilitated the dispersion of Fe species, thereby leading to an increase in the specific surface area, average pore size and pore volume of the catalysts. At the same time, trace Si addition can effectively improve the acid-base properties of the catalyst surface. All these changes may be beneficial to the catalytic degradation of the phenol simulated wastewater.

References

1. V. Vinayagam; K. N. Palani; S. Ganesh; S. Rajesh; V. V. Akula; R. Avoodaiappan; O. S. Kushwaha; A. Pugazhendhi; Environ. Res., 2024, 240, 117500.

2. K. M. AlAqad; M. M. Abdelnaby; A. Tanimu; I. Abdulazeez; A. M. Elsharif; Environ. Pollut. Manag., 2025, 2, 1-13.

3. T. Weng; H. Du; H. Luo; M. Jiang; Z. Chen; J. Wang; H. Chen; Sep. Purif. Technol., 2025, 355, 129573.

4. K. Haarstad; H. J. Bavor; T. Mæhlum; Water Sci. Technol., 2012, 65, 76–99.

5. B. Tunçsiper; J. Clean. Prod., 2019, 04, 211.‌ ‌

6. S. Yang; S. Yu; Y. Dong; J. Liu; P. Zhou; H. Zhang; Z. Xiong; C. S. He; B. Lai; J. Hazard. Mater., 2025, 490, 137752.

7. P. Koundle; N. Nirmalkar; G. Boczkaj; J. Environ. Manage., 2025, 374, 124107.

8. K. Tian; L. Hu; L. Li; Q. Zheng; Y. Xin; G. Zhang; Chinese Chem. Lett., 2022, 33, 4461-4477.

9. J. Nie; Z. Li; W. Liu; Z. Sang; D. A. Yang; L. Wang; F. Hou; J. Liang; Adv. Mater., 2025, 37, 2420236.

10. D. Ma; H. Yi; C. Lai; X. Liu; X. Huo; Z. An; L. Li; Y. Fu; B. Li; M. Zhang; L. Qin; S. Liu; L. Yang; Chemosphere, 2021, 275, 130104.

11. X. Zou; Q. Shi; M. Cheng; D. Huang; G. Zhang; W. Wang; G. Wang; H. Liu; Y. Chen; A. Chen; S. Deng; Adv. Energy Mater., 2025, 15, 2501424.

12. R. Lin; Y. Li; T. Yong; W. Cao; J. Wu; Y. Shen; J. Environ. Manage., 2022, 306, 114460.

13. F. N. Chergui; S. Ounoki; M. Chebbi; T. Masmoudi; Y. Kadmi; Int. J. Environ. Sci. Te., 2025, 22, 13717–13730.

14. Y. Zhu; R. Zhu; Y. Xi; J. Zhu; G. Zhu; H. He; Appl. Catal. B: Environ., 2019, 255, 117739.

15. H. Liu; S. Tang; Z. Wang; Q. Zhang; D. Yuan; Chemosphere, 2024, 353, 141581.

16. M. Zhang; H. Dong; L. Zhao; D. Wang; D. Meng; Sci. Total Environ., 2019, 670, 110-121.

17. J. Cai; J. Xiao; G. Du; Q. An; W. Tong; J. Mater. Chem. B, 2025, 13, 4544-4569.

18. X. Wang; D. Zhang; Y. Cheng; B. Wu; L. Sun; Molecules, 2025, 30, 4549.

19. J. Wang; C. Liu; J. Qi; J. Li; X. Sun; J. Shen; W. Han; L. Wang; Environ. Pollu., 2018, 243, 1068-1077.

20. L. Ma; Y. Wang; Y. Chen; D. Xu; R. Han; D. Jiao; H. Xing; D. Wang; X. Yang; ACS Nano., 2025, 19, 28410–28421.

21. P. Compton; N. R. Dehkordi; P. Larese Casanova; A. N. Alshawabkeh; J. Chem. Eng. Catal., 2022, 1: 203.

22. S. Guo; N. Yuan; G. Zhang; J. C. Yu; Micropor. Mesopor. Mater., 2017, 238, 62-68.

23. Q. U. Ain; U. Rasheed; Z. Chen; R. He; Z. Tong; J. Ind. Eng. Chem., 2024, 134, 327-342.

24. J. Zhao; K. Ding; B. Ding; Water Air Soil Poll., 2017, 228, 442.

25. N. K. Puthenveettil; G. Dražic; A. Pintar; N. N. Tušar; Catalysts, 2026, 16, 34.

26. N. Farhadian; S. Liu; A. Asadi; M. Shahlaei; S. Moradi; J. Mol. Liq., 2021, 321, 114896.

27. J. Zeng; W. Wang; Y. Du; Environ. Prog. Sustainable Energy, 2026, e70397.

28. S. T. Yang; W. Zhang; J. Xie; R. Liao; X. Zhang; B. Yu; R. Wu; X. Liu; H. Li; Z. Guo; RSC Adv., 2014, 5, 5337-5345.

29. Y. Chen; S. Zhang; Y. Chen; H. Ding; S. Yao; Y. Tang; Z. Qiu; K. Xu; Y. Hu; H. Pang; Nano Res., 2025, 18, 94907446.

30. B. Ma; Y. Zha; H. Shi; Y. Qin; M. Zhao; J. Li; S. Wang; B. Yan; B. Zhao; Y. Ma; H. Xie; Sep. Purif. Technol., 2025, 354, 129086.

31. B. Rezaei; M. Khamforoush; F. Rahmani; J. Clean. Prod., 2025, 513, 145744.

32. C. Xiao; Y. Han; Mat. Sci. Eng. A, 2002, 323, 58-61.

33. V. Calvino-Casilda; R. Martin-Aranda; I. Sobczak; M. Ziolek; Appl. Catal. A-Gen., 2006, 303, 121-130.

34. A. Cheng; Y. He; X. Liu; C. He; J. Environ. Sci., 2024, 136, 390-399.

35. X. Wang; Z. Yang; Y. Jiang; P. Zhao; X. Meng; Sep. Purif. Technol., 2024, 330, 125267.

36. M. Tian; X. Ren; S. Ding; N. Fu; Y. Wei; Z. Yang; X. Yao; Environ. Res., 2024, 243, 117848.

37. B. W. Chen; M. Mavrikakis; Nat. Chem. Eng., 2025, 2, 181-197.

38. M. Yaghi; S. Chidiac; S. Awad; Y. El Rayess; N. Zgheib; Clean Technol., 2025, 7, 62.

STUDIA UBB CHEMIA, Volume 71 (LXXI), No. 2, June 2026

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Published

2026-06-23

How to Cite

ZHAO, J., SHU, Y., JIA, L., ZHANG, X., LIU, M., LI, X., … LIAO, S. (2026). EFFECT OF TRACE SILICON ON THE PROPERTIES OF IRON-BASED HETEROGENEOUS FENTON CATALYSTS. Studia Universitatis Babeș-Bolyai Chemia, 71(2), 171–187. https://doi.org/10.24193/subbchem.2026.2.09

Issue

Volume 71, No. 2, 2026

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