THE INFLUENCE OF V2O5 ON SPECTROSCOPIC AND OPTICAL PROPERTIES OF MgO-KPO3 GLASSES CO-DOPED WITH Ag2O

Authors

  • Cristina SOMEȘAN Faculty of Physics, Babeş-Bolyai University, Cluj-Napoca, Romania. Corresponding authors: liviu.bolundut@chem.utcluj.ro, loredana.olar@usamvcluj.ro.
  • Liviu Călin BOLUNDUȚ Department of Physics and Chemistry, Technical University, Cluj-Napoca, Romania. Email: liviu.bolundut@chem.utcluj.ro. https://orcid.org/0000-0003-3539-0750
  • Loredana OLAR Faculty of Veterinary Medicine, University of Agiculture Sciences and Veterinary Medicine, Cluj-Napoca, Romania. Email: loredana.olar@usamvcluj.ro.
  • Vasile POP Department of Physics and Chemistry, Faculty of Materials Science and Engineering, Technical University, Cluj-Napoca, Romania. Email: vapop@phys.utcluj.ro.
  • Leontin DAVID Faculty of Physics, Babeş-Bolyai University, Cluj-Napoca, Romania. Email: leontin.david@phys.ubbcluj.ro. https://orcid.org/0009-0003-3901-1014

DOI:

https://doi.org/10.24193/subbchem.2020.2.13

Keywords:

V2O5-MgO-KPO3 glasses, X-ray diffraction, FT-IR, EPR, UV-vis analysis

Abstract

X-ray diffraction (XRD), Fourier transform infrared (FTIR), electron paramagnetic resonance (EPR), Ultraviolet-visible (UV-Vis) spectroscopies measurements have been employed to investigate the glasses from the (V2O5)x·(KPO3)80-x·(MgO)19·(Ag2O)1  (0 ≤ x ≤ 10 mol%) system. The studied glasses had a fixed MgO and Ag2O content of 19 mol% and 1 mol% respectively, and the V2O5:KPO3 ratio was varied. XRD data confirms the vitreous nature of the studied samples. EPR, UV-Vis and IR data confirm the presence of vanadium in multiple valence states.

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Published

2020-06-30

How to Cite

SOMEȘAN, C., BOLUNDUȚ, L. C. ., OLAR, L. ., POP, V. ., & DAVID, L. . (2020). THE INFLUENCE OF V2O5 ON SPECTROSCOPIC AND OPTICAL PROPERTIES OF MgO-KPO3 GLASSES CO-DOPED WITH Ag2O. Studia Universitatis Babeș-Bolyai Chemia, 65(2), 161–170. https://doi.org/10.24193/subbchem.2020.2.13

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