Thermodynamic Study of Some Alcohols in Dilute Aqueous Solution

Authors

  • Wedad J. FENDI Department of Chemistry, “Ibn-Al-Haitham” College of Education for Pure Science, University of Baghdad, Iraq. Corresponding author: husam.s.k@ihcoedu.uobaghdad.edu.iq.
  • Zainab Abbas AL-DULAIMY Department of Chemistry, “Ibn-Al-Haitham” College of Education for Pure Science, University of Baghdad, Iraq. Corresponding author: husam.s.k@ihcoedu.uobaghdad.edu.iq.
  • Dheefaf F. HASSAN Department of Chemistry, “Ibn-Al-Haitham” College of Education for Pure Science, University of Baghdad, Iraq. Corresponding author: husam.s.k@ihcoedu.uobaghdad.edu.iq. https://orcid.org/0000-0003-1872-3672
  • Azhar Farooq ABDULZAHRA Department of Chemistry, “Ibn-Al-Haitham” College of Education for Pure Science, University of Baghdad, Iraq. Corresponding author: husam.s.k@ihcoedu.uobaghdad.edu.iq.
  • Husam Saleem KHALAF Department of Chemistry, “Ibn-Al-Haitham” College of Education for Pure Science, University of Baghdad, Iraq. Email: husam.s.k@ihcoedu.uobaghdad.edu.iq. https://orcid.org/0000-0003-3932-3483

DOI:

https://doi.org/10.24193/subbchem.2023.4.09

Keywords:

Alcohols, Apparent molar volume, Modified Jone-Dole equation

Abstract

An apparent molar volume ϕv of 1-pentanol, 1-hexanol, 1-heptanol, and 1-octanol in dilute aqueous solution has been particular for density measurements at 298.15 K. A restrictive apparent molar volumes ϕv˚ at infinite dilution of these compounds were investigated based on Masson’s equation. Based on the Jone-Dole equation, A and B viscosity constants for four alcohols have been identified. This liquid offers resilient solute-solvent interaction. The modified Jone-Dole equation has also been employed with the experimental consequences using four liquids as solutes in dilute aqueous solutions.

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Published

2023-12-20

How to Cite

FENDI, W. J. ., AL-DULAIMY, Z. A. ., HASSAN, D. F. ., ABDULZAHRA, A. F. ., & KHALAF, H. S. . (2023). Thermodynamic Study of Some Alcohols in Dilute Aqueous Solution. Studia Universitatis Babeș-Bolyai Chemia, 68(4), 127–136. https://doi.org/10.24193/subbchem.2023.4.09

Issue

Volume 68, No. 4, 2023

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